Lithium Intercalation/Deintercalation of the Bi-2212 Phase by Electrochemical Method

Makoto Nakanishi; Yoshiaki Uwazumi; Masashi Fujiwara; Jun Takada; Yoshihiro Kusano; Yasuo Takeda; Yasunori Ikeda

doi:10.2497/jjspm.45.666

Lithium Intercalation/Deintercalation of the Bi-2212 Phase by Electrochemical Method

Makoto Nakanishi, Yoshiaki Uwazumi, Masashi Fujiwara, Jun Takada, Yoshihiro Kusano, Yasuo Takeda, Yasunori Ikeda

Environment Health & Safety Intelligence Department

Research output: Contribution to journal › Article › peer-review

Abstract

The effects of electrochemical removal reaction of lithium from the Li-doped Bi-2212 phase on its structure and superconducting properties have been studied. Lithium was inserted into and removed from Bi₂Sr_1.5,Ca_1.5Cu₂O_z through an electrochemical method at a constant applied potential at room temperature. The original crystal symmetry, tetragonal structure, was maintained and any secondary phase was not formed throughout the electrochemical reactions. Lattice parameter c of the doped samples, Li_xBi₂Sr_1.5Ca_1.5Cu₂O _z, decreased and T_c changed reversibly as the lithium content x decreased. It reveals that the electrochemical reactions were intercalation/deintercalation of the Bi-2212 phase with lithium.

Original language	English
Pages (from-to)	666-669
Number of pages	4
Journal	Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy
Volume	45
Issue number	7
DOIs	https://doi.org/10.2497/jjspm.45.666
Publication status	Published - Jul 1998

Keywords

Bi-2212 phase
Electrochemical reaction
Intercalation/deintercalation
Lattice parameter
T

ASJC Scopus subject areas

Mechanical Engineering
Industrial and Manufacturing Engineering
Metals and Alloys
Materials Chemistry

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10.2497/jjspm.45.666

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Lithium Intercalation/Deintercalation of the Bi-2212 Phase by Electrochemical Method. / Nakanishi, Makoto; Uwazumi, Yoshiaki; Fujiwara, Masashi; Takada, Jun; Kusano, Yoshihiro; Takeda, Yasuo; Ikeda, Yasunori.

In: Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy, Vol. 45, No. 7, 07.1998, p. 666-669.

Research output: Contribution to journal › Article › peer-review

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title = "Lithium Intercalation/Deintercalation of the Bi-2212 Phase by Electrochemical Method",

abstract = "The effects of electrochemical removal reaction of lithium from the Li-doped Bi-2212 phase on its structure and superconducting properties have been studied. Lithium was inserted into and removed from Bi2Sr1.5,Ca1.5Cu2Oz through an electrochemical method at a constant applied potential at room temperature. The original crystal symmetry, tetragonal structure, was maintained and any secondary phase was not formed throughout the electrochemical reactions. Lattice parameter c of the doped samples, LixBi2Sr1.5Ca1.5Cu2O z, decreased and Tc changed reversibly as the lithium content x decreased. It reveals that the electrochemical reactions were intercalation/deintercalation of the Bi-2212 phase with lithium.",

keywords = "Bi-2212 phase, Electrochemical reaction, Intercalation/deintercalation, Lattice parameter, T",

author = "Makoto Nakanishi and Yoshiaki Uwazumi and Masashi Fujiwara and Jun Takada and Yoshihiro Kusano and Yasuo Takeda and Yasunori Ikeda",

year = "1998",

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AU - Nakanishi, Makoto

AU - Uwazumi, Yoshiaki

AU - Fujiwara, Masashi

AU - Takada, Jun

AU - Kusano, Yoshihiro

AU - Takeda, Yasuo

AU - Ikeda, Yasunori

PY - 1998/7

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N2 - The effects of electrochemical removal reaction of lithium from the Li-doped Bi-2212 phase on its structure and superconducting properties have been studied. Lithium was inserted into and removed from Bi2Sr1.5,Ca1.5Cu2Oz through an electrochemical method at a constant applied potential at room temperature. The original crystal symmetry, tetragonal structure, was maintained and any secondary phase was not formed throughout the electrochemical reactions. Lattice parameter c of the doped samples, LixBi2Sr1.5Ca1.5Cu2O z, decreased and Tc changed reversibly as the lithium content x decreased. It reveals that the electrochemical reactions were intercalation/deintercalation of the Bi-2212 phase with lithium.

AB - The effects of electrochemical removal reaction of lithium from the Li-doped Bi-2212 phase on its structure and superconducting properties have been studied. Lithium was inserted into and removed from Bi2Sr1.5,Ca1.5Cu2Oz through an electrochemical method at a constant applied potential at room temperature. The original crystal symmetry, tetragonal structure, was maintained and any secondary phase was not formed throughout the electrochemical reactions. Lattice parameter c of the doped samples, LixBi2Sr1.5Ca1.5Cu2O z, decreased and Tc changed reversibly as the lithium content x decreased. It reveals that the electrochemical reactions were intercalation/deintercalation of the Bi-2212 phase with lithium.

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KW - Intercalation/deintercalation

KW - Lattice parameter

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Lithium Intercalation/Deintercalation of the Bi-2212 Phase by Electrochemical Method

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Keywords

ASJC Scopus subject areas

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