Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako; Masato Kodera; Hirotaka Nakajima; Kazuhiko Takai

doi:10.1002/adsc.201900215

Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako, Masato Kodera, Hirotaka Nakajima, Kazuhiko Takai

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

Original language	English
Journal	Advanced Synthesis and Catalysis
DOIs	https://doi.org/10.1002/adsc.201900215
Publication status	Published - Jan 1 2019

Keywords

2,2,6,6-tetramethylpiperidine
Brønsted base
deprotonation
Sodium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/adsc.201900215

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Asako, S., Kodera, M., Nakajima, H., & Takai, K. (2019). Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications. Advanced Synthesis and Catalysis. https://doi.org/10.1002/adsc.201900215

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