Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako, Masato Kodera, Hirotaka Nakajima, Kazuhiko Takai

Research output: Contribution to journal › Article

Abstract

Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

Original languageEnglish
JournalAdvanced Synthesis and Catalysis
DOIs
Publication statusPublished - Jan 1 2019

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Lithium
Sodium
2,2,6,6-tetramethylpiperidide

Keywords

  • 2,2,6,6-tetramethylpiperidine
  • Brønsted base
  • deprotonation
  • Sodium

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

Cite this

Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications. / Asako, Sobi; Kodera, Masato; Nakajima, Hirotaka; Takai, Kazuhiko.

In: Advanced Synthesis and Catalysis, 01.01.2019.

Research output: Contribution to journal › Article

Asako, S, Kodera, M, Nakajima, H & Takai, K 2019, 'Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications', Advanced Synthesis and Catalysis. https://doi.org/10.1002/adsc.201900215
Asako S, Kodera M, Nakajima H, Takai K. Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications. Advanced Synthesis and Catalysis. 2019 Jan 1. https://doi.org/10.1002/adsc.201900215
Asako, Sobi ; Kodera, Masato ; Nakajima, Hirotaka ; Takai, Kazuhiko. / Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications. In: Advanced Synthesis and Catalysis. 2019.
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