Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako; Masato Kodera; Hirotaka Nakajima; Kazuhiko Takai

doi:10.1002/adsc.201900215

Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako, Masato Kodera, Hirotaka Nakajima, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

Original language	English
Pages (from-to)	3120-3123
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	361
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201900215
Publication status	Published - Jul 2 2019

Keywords

2,2,6,6-tetramethylpiperidine
Brønsted base
Sodium
deprotonation

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/adsc.201900215

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title = "Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications",

abstract = "Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Br{\o}nsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).",

keywords = "2,2,6,6-tetramethylpiperidine, Br{\o}nsted base, Sodium, deprotonation",

author = "Sobi Asako and Masato Kodera and Hirotaka Nakajima and Kazuhiko Takai",

note = "Funding Information: We thank Okayama University and KOBELCO ECO-Solutions CO., Ltd. for financial support. Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2019",

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doi = "10.1002/adsc.201900215",

language = "English",

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AU - Asako, Sobi

AU - Kodera, Masato

AU - Nakajima, Hirotaka

AU - Takai, Kazuhiko

PY - 2019/7/2

Y1 - 2019/7/2

N2 - Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

AB - Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

KW - 2,2,6,6-tetramethylpiperidine

KW - Brønsted base

KW - Sodium

KW - deprotonation

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ER -

Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Abstract

Keywords

ASJC Scopus subject areas

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