Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako; Masato Kodera; Hirotaka Nakajima; Kazuhiko Takai

doi:10.1002/adsc.201900215

Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako, Masato Kodera, Hirotaka Nakajima, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

Original language	English
Pages (from-to)	3120-3123
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	361
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201900215
Publication status	Published - Jul 2 2019

Keywords

2,2,6,6-tetramethylpiperidine
Brønsted base
Sodium
deprotonation

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/adsc.201900215

Cite this

@article{c793cf60b0a048fa84ddcc22144f5a38,

title = "Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications",

abstract = "Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Br{\o}nsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).",

keywords = "2,2,6,6-tetramethylpiperidine, Br{\o}nsted base, Sodium, deprotonation",

author = "Sobi Asako and Masato Kodera and Hirotaka Nakajima and Kazuhiko Takai",

note = "Funding Information: We thank Okayama University and KOBELCO ECO-Solutions CO., Ltd. for financial support. Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2019",

month = jul,

day = "2",

doi = "10.1002/adsc.201900215",

language = "English",

volume = "361",

pages = "3120--3123",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

publisher = "Wiley-VCH Verlag",

number = "13",

}

TY - JOUR

T1 - Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

AU - Asako, Sobi

AU - Kodera, Masato

AU - Nakajima, Hirotaka

AU - Takai, Kazuhiko

PY - 2019/7/2

Y1 - 2019/7/2

N2 - Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

AB - Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

KW - 2,2,6,6-tetramethylpiperidine

KW - Brønsted base

KW - Sodium

KW - deprotonation

UR - http://www.scopus.com/inward/record.url?scp=85065764857&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85065764857&partnerID=8YFLogxK

U2 - 10.1002/adsc.201900215

DO - 10.1002/adsc.201900215

M3 - Article

AN - SCOPUS:85065764857

VL - 361

SP - 3120

EP - 3123

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

SN - 1615-4150

IS - 13

ER -

Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this