Lithium-Free Synthesis of Sodium 2,2,6,6-Tetramethylpiperidide and Its Synthetic Applications

Sobi Asako, Masato Kodera, Hirotaka Nakajima, Kazuhiko Takai

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Lithium-free synthetic methods for sodium 2,2,6,6-tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP. (Figure presented.).

Original languageEnglish
Pages (from-to)3120-3123
Number of pages4
JournalAdvanced Synthesis and Catalysis
Volume361
Issue number13
DOIs
Publication statusPublished - Jul 2 2019

Keywords

  • 2,2,6,6-tetramethylpiperidine
  • Brønsted base
  • Sodium
  • deprotonation

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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