Lithium, boron and lead isotope and trace element systematics of Quaternary basaltic volcanic rocks in northeastern Japan: Mineralogical controls on slab-derived fluid composition

Takuya Moriguti, Tomoyuki Shibata, Eizou Nakamura

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76 Citations (Scopus)

Abstract

Across-arc Li-B-Pb isotope systematics, together with trace element geochemistry and phase relationships in subducting slabs are used to understand the petrogenesis of lavas from the northeastern Japan arc. Pb/Nb ratios and Pb isotope compositions of the arc lavas decrease with depth to slab whereas Li/Y, U/Nb, Th/Nb and La/Sm show an upward profile across the arc, with peaks at 180 km depth to the Wadati-Benioff zone (WBZ). The peaks in these profiles may reflect the influence of lawsonite breakdown in the slab at 180 km depth. B/Nb ratios of the arc lavas do not show clear across-arc variation and the δ11B values show a concave upward across-arc profile with minimum values at around 180 km in depth of the WBZ. These results possibly reflect the decomposition of tourmaline at ∼180 km. Our results suggest that accessory minerals and minor phases in the subducting slab play important roles in determining the chemical compositions of fluid released by dehydration, and the resulting trace element and isotope composition of arc lavas. Li isotope compositions of the lavas are MORB-like and do not show systematic across-arc variation, contrasting with Izu arc lavas, which show maximum δ7Li values at the volcanic front and a systematic decrease towards the back arc. The strikingly different results for the northeastern Japan arc and the Izu arc are likely to be caused by differing extents of Li isotope fractionation due to differing subduction zone physical characteristics, such as thermal structure of the subducting slab and subduction angle. Thus, not only chemical characteristics of the subducting slab but also the physical, as well as chemical characteristics of the subduction zone could affect the Li isotope compositions of subducting slabs, producing heterogeneity in the Li isotope composition of the mantle.

Original languageEnglish
Pages (from-to)81-100
Number of pages20
JournalChemical Geology
Volume212
Issue number1-2
DOIs
Publication statusPublished - Nov 26 2004

Fingerprint

boron isotope
Volcanic rocks
Boron
fluid composition
lead isotope
Trace Elements
lithium
Lithium
Isotopes
slab
volcanic rock
trace element
isotope
Fluids
Chemical analysis
Benioff zone
subduction zone
lawsonite
Geochemistry
accessory mineral

Keywords

  • Boron isotopes
  • Li isotopes
  • Northeastern Japan arc
  • Subducting slab
  • Trace elements

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

@article{5435e8326c3c4ceb8c7c1b088662b99a,
title = "Lithium, boron and lead isotope and trace element systematics of Quaternary basaltic volcanic rocks in northeastern Japan: Mineralogical controls on slab-derived fluid composition",
abstract = "Across-arc Li-B-Pb isotope systematics, together with trace element geochemistry and phase relationships in subducting slabs are used to understand the petrogenesis of lavas from the northeastern Japan arc. Pb/Nb ratios and Pb isotope compositions of the arc lavas decrease with depth to slab whereas Li/Y, U/Nb, Th/Nb and La/Sm show an upward profile across the arc, with peaks at 180 km depth to the Wadati-Benioff zone (WBZ). The peaks in these profiles may reflect the influence of lawsonite breakdown in the slab at 180 km depth. B/Nb ratios of the arc lavas do not show clear across-arc variation and the δ11B values show a concave upward across-arc profile with minimum values at around 180 km in depth of the WBZ. These results possibly reflect the decomposition of tourmaline at ∼180 km. Our results suggest that accessory minerals and minor phases in the subducting slab play important roles in determining the chemical compositions of fluid released by dehydration, and the resulting trace element and isotope composition of arc lavas. Li isotope compositions of the lavas are MORB-like and do not show systematic across-arc variation, contrasting with Izu arc lavas, which show maximum δ7Li values at the volcanic front and a systematic decrease towards the back arc. The strikingly different results for the northeastern Japan arc and the Izu arc are likely to be caused by differing extents of Li isotope fractionation due to differing subduction zone physical characteristics, such as thermal structure of the subducting slab and subduction angle. Thus, not only chemical characteristics of the subducting slab but also the physical, as well as chemical characteristics of the subduction zone could affect the Li isotope compositions of subducting slabs, producing heterogeneity in the Li isotope composition of the mantle.",
keywords = "Boron isotopes, Li isotopes, Northeastern Japan arc, Subducting slab, Trace elements",
author = "Takuya Moriguti and Tomoyuki Shibata and Eizou Nakamura",
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language = "English",
volume = "212",
pages = "81--100",
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TY - JOUR

T1 - Lithium, boron and lead isotope and trace element systematics of Quaternary basaltic volcanic rocks in northeastern Japan

T2 - Mineralogical controls on slab-derived fluid composition

AU - Moriguti, Takuya

AU - Shibata, Tomoyuki

AU - Nakamura, Eizou

PY - 2004/11/26

Y1 - 2004/11/26

N2 - Across-arc Li-B-Pb isotope systematics, together with trace element geochemistry and phase relationships in subducting slabs are used to understand the petrogenesis of lavas from the northeastern Japan arc. Pb/Nb ratios and Pb isotope compositions of the arc lavas decrease with depth to slab whereas Li/Y, U/Nb, Th/Nb and La/Sm show an upward profile across the arc, with peaks at 180 km depth to the Wadati-Benioff zone (WBZ). The peaks in these profiles may reflect the influence of lawsonite breakdown in the slab at 180 km depth. B/Nb ratios of the arc lavas do not show clear across-arc variation and the δ11B values show a concave upward across-arc profile with minimum values at around 180 km in depth of the WBZ. These results possibly reflect the decomposition of tourmaline at ∼180 km. Our results suggest that accessory minerals and minor phases in the subducting slab play important roles in determining the chemical compositions of fluid released by dehydration, and the resulting trace element and isotope composition of arc lavas. Li isotope compositions of the lavas are MORB-like and do not show systematic across-arc variation, contrasting with Izu arc lavas, which show maximum δ7Li values at the volcanic front and a systematic decrease towards the back arc. The strikingly different results for the northeastern Japan arc and the Izu arc are likely to be caused by differing extents of Li isotope fractionation due to differing subduction zone physical characteristics, such as thermal structure of the subducting slab and subduction angle. Thus, not only chemical characteristics of the subducting slab but also the physical, as well as chemical characteristics of the subduction zone could affect the Li isotope compositions of subducting slabs, producing heterogeneity in the Li isotope composition of the mantle.

AB - Across-arc Li-B-Pb isotope systematics, together with trace element geochemistry and phase relationships in subducting slabs are used to understand the petrogenesis of lavas from the northeastern Japan arc. Pb/Nb ratios and Pb isotope compositions of the arc lavas decrease with depth to slab whereas Li/Y, U/Nb, Th/Nb and La/Sm show an upward profile across the arc, with peaks at 180 km depth to the Wadati-Benioff zone (WBZ). The peaks in these profiles may reflect the influence of lawsonite breakdown in the slab at 180 km depth. B/Nb ratios of the arc lavas do not show clear across-arc variation and the δ11B values show a concave upward across-arc profile with minimum values at around 180 km in depth of the WBZ. These results possibly reflect the decomposition of tourmaline at ∼180 km. Our results suggest that accessory minerals and minor phases in the subducting slab play important roles in determining the chemical compositions of fluid released by dehydration, and the resulting trace element and isotope composition of arc lavas. Li isotope compositions of the lavas are MORB-like and do not show systematic across-arc variation, contrasting with Izu arc lavas, which show maximum δ7Li values at the volcanic front and a systematic decrease towards the back arc. The strikingly different results for the northeastern Japan arc and the Izu arc are likely to be caused by differing extents of Li isotope fractionation due to differing subduction zone physical characteristics, such as thermal structure of the subducting slab and subduction angle. Thus, not only chemical characteristics of the subducting slab but also the physical, as well as chemical characteristics of the subduction zone could affect the Li isotope compositions of subducting slabs, producing heterogeneity in the Li isotope composition of the mantle.

KW - Boron isotopes

KW - Li isotopes

KW - Northeastern Japan arc

KW - Subducting slab

KW - Trace elements

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U2 - 10.1016/j.chemgeo.2004.08.005

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