Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide

Tomoyuki Tajima, Shoko Yamamoto, Yuta Sakamoto, Shoji Takagi, Toshitaka Nakaya, Yutaka Takaguchi, Asako Igashira-Kamiyama, Nobuto Yoshinari, Takumi Konno

Research output: Contribution to journalArticle

Abstract

The reaction of (Me4N)4[Cd10S4(SPh)16] (1) with diphenyl diselenide (2) in propionitrile afforded a molecular cluster, (Me4N)4[Cd10S4(SePh)16] (3), the structure of which was determined by X-ray crystallography. Ligand exchange proceeded in a heterogeneous reaction system, and the use of a less polar solvent appeared to be crucial for the synthesis of 3 to prevent degradation of the Cd10S4Se16 cluster core.

Original languageEnglish
Pages (from-to)384-386
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume90
Issue number4
DOIs
Publication statusPublished - 2017

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X ray crystallography
Ligands
Degradation
diphenyldiselenide
propionitrile

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide. / Tajima, Tomoyuki; Yamamoto, Shoko; Sakamoto, Yuta; Takagi, Shoji; Nakaya, Toshitaka; Takaguchi, Yutaka; Igashira-Kamiyama, Asako; Yoshinari, Nobuto; Konno, Takumi.

In: Bulletin of the Chemical Society of Japan, Vol. 90, No. 4, 2017, p. 384-386.

Research output: Contribution to journalArticle

Tajima, T, Yamamoto, S, Sakamoto, Y, Takagi, S, Nakaya, T, Takaguchi, Y, Igashira-Kamiyama, A, Yoshinari, N & Konno, T 2017, 'Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide', Bulletin of the Chemical Society of Japan, vol. 90, no. 4, pp. 384-386. https://doi.org/10.1246/bcsj.20160395
Tajima, Tomoyuki ; Yamamoto, Shoko ; Sakamoto, Yuta ; Takagi, Shoji ; Nakaya, Toshitaka ; Takaguchi, Yutaka ; Igashira-Kamiyama, Asako ; Yoshinari, Nobuto ; Konno, Takumi. / Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide. In: Bulletin of the Chemical Society of Japan. 2017 ; Vol. 90, No. 4. pp. 384-386.
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