Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide

Tomoyuki Tajima, Shoko Yamamoto, Yuta Sakamoto, Shoji Takagi, Toshitaka Nakaya, Yutaka Takaguchi, Asako Igashira-Kamiyama, Nobuto Yoshinari, Takumi Konno

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of (Me4N)4[Cd10S4(SPh)16] (1) with diphenyl diselenide (2) in propionitrile afforded a molecular cluster, (Me4N)4[Cd10S4(SePh)16] (3), the structure of which was determined by X-ray crystallography. Ligand exchange proceeded in a heterogeneous reaction system, and the use of a less polar solvent appeared to be crucial for the synthesis of 3 to prevent degradation of the Cd10S4Se16 cluster core.

Original languageEnglish
Pages (from-to)384-386
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume90
Issue number4
DOIs
Publication statusPublished - 2017

ASJC Scopus subject areas

  • Chemistry(all)

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