Abstract
A novel type of nucleophilic addition of ketene silyl acetals (2) to N-acyliminium ion intermediate, which could be generated by the action of catalytic TiCl4 to ethyl 2-(N-benzyloxycarbonylamino)methylene-3-oxobutanoate (1) in CH2Cl2 at -78°C, has been realized.
| Original language | English |
|---|---|
| Pages (from-to) | 1103-1105 |
| Number of pages | 3 |
| Journal | Synlett |
| Volume | 1996 |
| Issue number | 11 |
| Publication status | Published - 1996 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Lewis Acid-Promoted Generation of an Iminium ion from Ethyl 2-(N-Benzyloxycarbonylamino)-methylene-3-oxobutanoate and Its Reactions with Ketene Silyl Acetals. / Saito, Seiki; Uedo, Eiji; Kato, Yoshitaka; Murakami, Yoshinori; Ishikawa, Teruhiko.
In: Synlett, Vol. 1996, No. 11, 1996, p. 1103-1105.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Lewis Acid-Promoted Generation of an Iminium ion from Ethyl 2-(N-Benzyloxycarbonylamino)-methylene-3-oxobutanoate and Its Reactions with Ketene Silyl Acetals
AU - Saito, Seiki
AU - Uedo, Eiji
AU - Kato, Yoshitaka
AU - Murakami, Yoshinori
AU - Ishikawa, Teruhiko
PY - 1996
Y1 - 1996
N2 - A novel type of nucleophilic addition of ketene silyl acetals (2) to N-acyliminium ion intermediate, which could be generated by the action of catalytic TiCl4 to ethyl 2-(N-benzyloxycarbonylamino)methylene-3-oxobutanoate (1) in CH2Cl2 at -78°C, has been realized.
AB - A novel type of nucleophilic addition of ketene silyl acetals (2) to N-acyliminium ion intermediate, which could be generated by the action of catalytic TiCl4 to ethyl 2-(N-benzyloxycarbonylamino)methylene-3-oxobutanoate (1) in CH2Cl2 at -78°C, has been realized.
UR - http://www.scopus.com/inward/record.url?scp=0008861249&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0008861249&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0008861249
VL - 1996
SP - 1103
EP - 1105
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 11
ER -