Kinetic studies of specific solvent effect on the thermal isomerization of palladium dithizonate in toluene-alcohol mixtures

Yoshimi Sueishi, Yoko Takashima, Shunzo Yamamoto

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The kinetics of the thermal isomerization of palladium dithizonate (Pd(HDz)2) in the binary mixture of toluene and alcohols has been studied. In the solvent effects on the Pd(HDz)2 isomerization rates, we found that the maximum lies in the range x = 0.02 to approximately 0.2 (x represents the mole fraction of alcohols). The experimental kinetic data for the specific solvent effect with maximum can be reproduced well by taking into account hydrogen bonding and coordination of alcohols with Pd(HDz)2. The rate constants for the thermal isomerization of Pd(HDz)2 involving hydrogen bonding and the coordinate interaction with 1-butanol are evaluated.

Original languageEnglish
Pages (from-to)542-547
Number of pages6
JournalInternational Journal of Chemical Kinetics
Volume32
Issue number9
DOIs
Publication statusPublished - Sep 2000

Fingerprint

Toluene
Palladium
Isomerization
isomerization
toluene
palladium
alcohols
Alcohols
Hot Temperature
Hydrogen Bonding
Kinetics
Hydrogen bonds
kinetics
1-Butanol
hydrogen
Binary mixtures
Butenes
binary mixtures
Rate constants
interactions

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Kinetic studies of specific solvent effect on the thermal isomerization of palladium dithizonate in toluene-alcohol mixtures. / Sueishi, Yoshimi; Takashima, Yoko; Yamamoto, Shunzo.

In: International Journal of Chemical Kinetics, Vol. 32, No. 9, 09.2000, p. 542-547.

Research output: Contribution to journalArticle

@article{dcf1c2035f9c45aa8f508a82d2b0fb5a,
title = "Kinetic studies of specific solvent effect on the thermal isomerization of palladium dithizonate in toluene-alcohol mixtures",
abstract = "The kinetics of the thermal isomerization of palladium dithizonate (Pd(HDz)2) in the binary mixture of toluene and alcohols has been studied. In the solvent effects on the Pd(HDz)2 isomerization rates, we found that the maximum lies in the range x = 0.02 to approximately 0.2 (x represents the mole fraction of alcohols). The experimental kinetic data for the specific solvent effect with maximum can be reproduced well by taking into account hydrogen bonding and coordination of alcohols with Pd(HDz)2. The rate constants for the thermal isomerization of Pd(HDz)2 involving hydrogen bonding and the coordinate interaction with 1-butanol are evaluated.",
author = "Yoshimi Sueishi and Yoko Takashima and Shunzo Yamamoto",
year = "2000",
month = "9",
doi = "10.1002/1097-4601(2000)32:9<542::AID-KIN4>3.0.CO;2-9",
language = "English",
volume = "32",
pages = "542--547",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "John Wiley and Sons Inc.",
number = "9",

}

TY - JOUR

T1 - Kinetic studies of specific solvent effect on the thermal isomerization of palladium dithizonate in toluene-alcohol mixtures

AU - Sueishi, Yoshimi

AU - Takashima, Yoko

AU - Yamamoto, Shunzo

PY - 2000/9

Y1 - 2000/9

N2 - The kinetics of the thermal isomerization of palladium dithizonate (Pd(HDz)2) in the binary mixture of toluene and alcohols has been studied. In the solvent effects on the Pd(HDz)2 isomerization rates, we found that the maximum lies in the range x = 0.02 to approximately 0.2 (x represents the mole fraction of alcohols). The experimental kinetic data for the specific solvent effect with maximum can be reproduced well by taking into account hydrogen bonding and coordination of alcohols with Pd(HDz)2. The rate constants for the thermal isomerization of Pd(HDz)2 involving hydrogen bonding and the coordinate interaction with 1-butanol are evaluated.

AB - The kinetics of the thermal isomerization of palladium dithizonate (Pd(HDz)2) in the binary mixture of toluene and alcohols has been studied. In the solvent effects on the Pd(HDz)2 isomerization rates, we found that the maximum lies in the range x = 0.02 to approximately 0.2 (x represents the mole fraction of alcohols). The experimental kinetic data for the specific solvent effect with maximum can be reproduced well by taking into account hydrogen bonding and coordination of alcohols with Pd(HDz)2. The rate constants for the thermal isomerization of Pd(HDz)2 involving hydrogen bonding and the coordinate interaction with 1-butanol are evaluated.

UR - http://www.scopus.com/inward/record.url?scp=0034274663&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034274663&partnerID=8YFLogxK

U2 - 10.1002/1097-4601(2000)32:9<542::AID-KIN4>3.0.CO;2-9

DO - 10.1002/1097-4601(2000)32:9<542::AID-KIN4>3.0.CO;2-9

M3 - Article

VL - 32

SP - 542

EP - 547

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 9

ER -