Kinetic gate-opening process in a flexible porous coordination polymer

Daisuke Tanaka, Keiji Nakagawa, Masakazu Higuchi, Satoshi Horike, Yoshiki Kubota, Tatsuo Kobayashi, Masaki Takata, Susumu Kitagawa

Research output: Contribution to journalArticle

229 Citations (Scopus)

Abstract

(Graph Presented) Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.

Original languageEnglish
Pages (from-to)3914-3918
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number21
DOIs
Publication statusPublished - May 13 2008

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Polymers
Adsorption
Kinetics
Adsorption isotherms
Gases
Molecules

Keywords

  • Adsorption
  • Coordination polymers
  • Kinetics
  • Microporous materials
  • Phase transition

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Tanaka, D., Nakagawa, K., Higuchi, M., Horike, S., Kubota, Y., Kobayashi, T., ... Kitagawa, S. (2008). Kinetic gate-opening process in a flexible porous coordination polymer. Angewandte Chemie - International Edition, 47(21), 3914-3918. https://doi.org/10.1002/anie.200705822

Kinetic gate-opening process in a flexible porous coordination polymer. / Tanaka, Daisuke; Nakagawa, Keiji; Higuchi, Masakazu; Horike, Satoshi; Kubota, Yoshiki; Kobayashi, Tatsuo; Takata, Masaki; Kitagawa, Susumu.

In: Angewandte Chemie - International Edition, Vol. 47, No. 21, 13.05.2008, p. 3914-3918.

Research output: Contribution to journalArticle

Tanaka, D, Nakagawa, K, Higuchi, M, Horike, S, Kubota, Y, Kobayashi, T, Takata, M & Kitagawa, S 2008, 'Kinetic gate-opening process in a flexible porous coordination polymer', Angewandte Chemie - International Edition, vol. 47, no. 21, pp. 3914-3918. https://doi.org/10.1002/anie.200705822
Tanaka, Daisuke ; Nakagawa, Keiji ; Higuchi, Masakazu ; Horike, Satoshi ; Kubota, Yoshiki ; Kobayashi, Tatsuo ; Takata, Masaki ; Kitagawa, Susumu. / Kinetic gate-opening process in a flexible porous coordination polymer. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 21. pp. 3914-3918.
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