Ketone synthesis by intramolecular acylation of organorhodium(I) with Ester

Tomoya Miura, Taisuke Sasaki, Hiroki Nakazawa, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

113 Citations (Scopus)

Abstract

New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with an ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon-carbon bond formation. The reactions ended up with generation of an alkoxyrhodium(I) species to promote the next catalytic cycle.

Original languageEnglish
Pages (from-to)1390-1391
Number of pages2
JournalJournal of the American Chemical Society
Volume127
Issue number5
DOIs
Publication statusPublished - Feb 9 2005
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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