Katsuki-Sharpless asymmetric epoxidation of alkenylethylene glycols: The origin of inverted stereoselection

Takehiko Yoshimitsu, Kunio Ogasawara

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti 2(tartrate)2 complex.

Original languageEnglish
Pages (from-to)2197-2199
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
DOIs
Publication statusPublished - 1994
Externally publishedYes

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Glycols
Epoxidation
Titanium
Atoms
Substrates
tartaric acid

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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abstract = "The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti 2(tartrate)2 complex.",
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