Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules

Toshiki Nokami; Kousuke Ohata; Masafumi Inoue; Hiroaki Tsuyama; Akito Shibuya; Kazuya Soga; Masayuki Okajima; Seiji Suga; Jun Ichi Yoshida

doi:10.1021/ja803487q

Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules

Toshiki Nokami, Kousuke Ohata, Masafumi Inoue, Hiroaki Tsuyama, Akito Shibuya, Kazuya Soga, Masayuki Okajima, Seiji Suga, Jun Ichi Yoshida

Research output: Contribution to journal › Article

53 Citations (Scopus)

Abstract

An iterative method for molecular assembly has been developed based on the cation-pool method using (trimethylsilyl)diphenylmethane as a building block. The silyl group works as both an activating group of the benzene ring in the Friedel-Crafts type reaction and an electroauxiliary in the subsequent low temperature anodic oxidation to generate dendritic diarylcarbenium ions, which were well characterized by low-temperature NMR spectroscopy. The convergent synthesis of dendritic molecules has been achieved by repeating the sequence.

Original language	English
Pages (from-to)	10864-10865
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	33
DOIs	https://doi.org/10.1021/ja803487q
Publication status	Published - Aug 20 2008
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja803487q

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Nokami, T., Ohata, K., Inoue, M., Tsuyama, H., Shibuya, A., Soga, K., Okajima, M., Suga, S., & Yoshida, J. I. (2008). Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules. Journal of the American Chemical Society, 130(33), 10864-10865. https://doi.org/10.1021/ja803487q

Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules. / Nokami, Toshiki; Ohata, Kousuke; Inoue, Masafumi; Tsuyama, Hiroaki; Shibuya, Akito; Soga, Kazuya; Okajima, Masayuki; Suga, Seiji; Yoshida, Jun Ichi.

In: Journal of the American Chemical Society, Vol. 130, No. 33, 20.08.2008, p. 10864-10865.

Research output: Contribution to journal › Article

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