Isothermal compression of face-centered cubic iron

Yu Nishihara, Yoichi Nakajima, Akihiko Akashi, Noriyoshi Tsujino, Eiichi Takahashi, Ken Ichi Funakoshi, Yuji Higo

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

Isothermal compression curves of face-centered cubic iron (γ-Fe) were determined at high temperatures (1273 and 1073 K) up to 27 GPa by in situ X-ray diffraction experiments using synchrotron radiation and the Kawai-type multi-anvil apparatus. Fits of the third-order Birch-Murnaghan equation of state to pressure-volume data yielded V0 = 48.997 ± 0.040 A 3, K T0 = 108.3 ± 2.4 GPa, and K T? = 5.8 ± 0.2 for 1273 K, and V0 = 48.600 ± 0.098 A 3, K T0 = 88.9 ± 5.1 GPa, and KT? = 8.9 ± 0.7 for 1073 K, where V 0, K T0, and K T? are unit-cell volume, bulk modulus and its pressure derivative, respectively, at ambient pressure. The relatively large values of K T? are attributable to successive electronic spin state transitions from mixed-spin at lower pressures to low-spin at higher pressures. When discussing the constituents of Earth's (or other planets') solid inner core in terms of density and equations of state, one must carefully consider the influence of the electronic spin state.

Original languageEnglish
Pages (from-to)1417-1420
Number of pages4
JournalAmerican Mineralogist
Volume97
Issue number8-9
DOIs
Publication statusPublished - Aug 2012

Keywords

  • Compression curve
  • Face-centered cubic (fcc) iron
  • High pressure
  • Inner core
  • Spin transition

ASJC Scopus subject areas

  • Geophysics
  • Geochemistry and Petrology

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