Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst

Seijiro Matsubara, Kazuhiko Takai, Hitosi Nozaki

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. → sec. have been examined.

Original languageEnglish
Pages (from-to)3741-3744
Number of pages4
JournalTetrahedron Letters
Volume24
Issue number35
DOIs
Publication statusPublished - 1983
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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