Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst

Seijiro Matsubara, Kazuhiko Takai, Hitosi Nozaki

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. → sec. have been examined.

Original languageEnglish
Pages (from-to)3741-3744
Number of pages4
JournalTetrahedron Letters
Volume24
Issue number35
DOIs
Publication statusPublished - 1983
Externally publishedYes

Fingerprint

Methylene Chloride
Isomerization
Isomers
Catalysts
bis(acetylacetonato)oxovanadium(IV)
allyl alcohol

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst. / Matsubara, Seijiro; Takai, Kazuhiko; Nozaki, Hitosi.

In: Tetrahedron Letters, Vol. 24, No. 35, 1983, p. 3741-3744.

Research output: Contribution to journalArticle

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