Abstract
A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.
Original language | English |
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Pages (from-to) | 5128-5132 |
Number of pages | 5 |
Journal | Organometallics |
Volume | 17 |
Issue number | 23 |
DOIs | |
Publication status | Published - Jan 1 1998 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry