Isolation and reactions of a tantalum-imine complex TaCl3(dme) (PhCH=NCH2Ph)

Kazuhiko Takai; Takaya Ishiyama; Hidekuni Yasue; Takahumi Nobunaka; Makoto Itoh; Toshiyuki Oshiki; Kazushi Mashima; Kazuhide Tani

doi:10.1021/om980380l

Isolation and reactions of a tantalum-imine complex TaCl₃(dme) (PhCH=NCH₂Ph)

Kazuhiko Takai, Takaya Ishiyama, Hidekuni Yasue, Takahumi Nobunaka, Makoto Itoh, Toshiyuki Oshiki, Kazushi Mashima, Kazuhide Tani

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

A new tantalum-imine complex TaCl₃(dme)(PhCH=NCH₂Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl₅ and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

Original language	English
Pages (from-to)	5128-5132
Number of pages	5
Journal	Organometallics
Volume	17
Issue number	23
DOIs	https://doi.org/10.1021/om980380l
Publication status	Published - Jan 1 1998

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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Takai, K., Ishiyama, T., Yasue, H., Nobunaka, T., Itoh, M., Oshiki, T., Mashima, K., & Tani, K. (1998). Isolation and reactions of a tantalum-imine complex TaCl₃(dme) (PhCH=NCH₂Ph). Organometallics, 17(23), 5128-5132. https://doi.org/10.1021/om980380l

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AU - Nobunaka, Takahumi

AU - Itoh, Makoto

AU - Oshiki, Toshiyuki

AU - Mashima, Kazushi

AU - Tani, Kazuhide

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