Isolation and reactions of a tantalum-imine complex TaCl3(dme) (PhCH=NCH2Ph)

Kazuhiko Takai; Takaya Ishiyama; Hidekuni Yasue; Takahumi Nobunaka; Makoto Itoh; Toshiyuki Oshiki; Kazushi Mashima; Kazuhide Tani

doi:10.1021/om980380l

Isolation and reactions of a tantalum-imine complex TaCl₃(dme) (PhCH=NCH₂Ph)

Kazuhiko Takai, Takaya Ishiyama, Hidekuni Yasue, Takahumi Nobunaka, Makoto Itoh, Toshiyuki Oshiki, Kazushi Mashima, Kazuhide Tani

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

A new tantalum-imine complex TaCl₃(dme)(PhCH=NCH₂Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl₅ and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

Original language	English
Pages (from-to)	5128-5132
Number of pages	5
Journal	Organometallics
Volume	17
Issue number	23
DOIs	https://doi.org/10.1021/om980380l
Publication status	Published - Jan 1 1998
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om980380l

Cite this

@article{b554afceee6b456689b35d44c85eb8bc,

title = "Isolation and reactions of a tantalum-imine complex TaCl3(dme) (PhCH=NCH2Ph)",

abstract = "A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.",

author = "Kazuhiko Takai and Takaya Ishiyama and Hidekuni Yasue and Takahumi Nobunaka and Makoto Itoh and Toshiyuki Oshiki and Kazushi Mashima and Kazuhide Tani",

year = "1998",

month = jan,

day = "1",

doi = "10.1021/om980380l",

language = "English",

volume = "17",

pages = "5128--5132",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Isolation and reactions of a tantalum-imine complex TaCl3(dme) (PhCH=NCH2Ph)

AU - Takai, Kazuhiko

AU - Ishiyama, Takaya

AU - Yasue, Hidekuni

AU - Nobunaka, Takahumi

AU - Itoh, Makoto

AU - Oshiki, Toshiyuki

AU - Mashima, Kazushi

AU - Tani, Kazuhide

PY - 1998/1/1

Y1 - 1998/1/1

N2 - A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

AB - A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

UR - http://www.scopus.com/inward/record.url?scp=0000462989&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000462989&partnerID=8YFLogxK

U2 - 10.1021/om980380l

DO - 10.1021/om980380l

M3 - Article

AN - SCOPUS:0000462989

VL - 17

SP - 5128

EP - 5132

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 23

ER -

Isolation and reactions of a tantalum-imine complex TaCl₃(dme) (PhCH=NCH₂Ph)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this