Isolation and reactions of a tantalum-imine complex TaCl3(dme) (PhCH=NCH2Ph)

Kazuhiko Takai; Takaya Ishiyama; Hidekuni Yasue; Takahumi Nobunaka; Makoto Itoh; Toshiyuki Oshiki; Kazushi Mashima; Kazuhide Tani

doi:10.1021/om980380l

Isolation and reactions of a tantalum-imine complex TaCl₃(dme) (PhCH=NCH₂Ph)

Kazuhiko Takai, Takaya Ishiyama, Hidekuni Yasue, Takahumi Nobunaka, Makoto Itoh, Toshiyuki Oshiki, Kazushi Mashima, Kazuhide Tani

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

A new tantalum-imine complex TaCl₃(dme)(PhCH=NCH₂Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl₅ and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

Original language	English
Pages (from-to)	5128-5132
Number of pages	5
Journal	Organometallics
Volume	17
Issue number	23
DOIs	https://doi.org/10.1021/om980380l
Publication status	Published - Jan 1 1998

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.",

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AU - Takai, Kazuhiko

AU - Ishiyama, Takaya

AU - Yasue, Hidekuni

AU - Nobunaka, Takahumi

AU - Itoh, Makoto

AU - Oshiki, Toshiyuki

AU - Mashima, Kazushi

AU - Tani, Kazuhide

PY - 1998/1/1

Y1 - 1998/1/1

N2 - A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

AB - A new tantalum-imine complex TaCl3(dme)(PhCH=NCH2Ph) (1) (DME = 1,2-dimethoxyethane) was synthesized by treatment of N-(benzylidene)benzylamine with low-valent tantalum derived from TaCl5 and zinc in DME and toluene. The molecular structure of complex 1 was determined by X-ray crystallographic analysis, and its reactivity toward unsaturated compounds examined.

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Isolation and reactions of a tantalum-imine complex TaCl₃(dme) (PhCH=NCH₂Ph)

Abstract

ASJC Scopus subject areas

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