Irradiation effect of synchrotron radiation on crystallization of thin amorphous WO3 film

Yuki Kimura, Katsumi Hanamoto, Yasuyuki Nakayama, Chihiro Kaito

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In order to elucidate the effect of synchrotron radiation (SR) irradiation on crystal growth, crystallization of WO3 films has been performed in vacuum under SR irradiation. The main results were compared with the results of heat treatment of the same film. Upon SR irradiation for 80 s using a toroidal mirror, a catastrophic change occurred, i.e. W3O crystals (A-15 type) with a size of less than 30 nm appeared. Decomposition of the WO3 film started at above 750 °C during vacuum heating. W, WO2 and incommensurate WO3 crystals appeared. W3O crystal produced neither intense electron beam irradiation nor vacuum heating. These results will be discussed in terms of the differences caused by excitation with a SR beam, i.e. strong inner shell excitation and ionization of W and O may have taken place.

Original languageEnglish
Pages (from-to)187-192
Number of pages6
JournalNuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume194
Issue number2
DOIs
Publication statusPublished - Aug 2002

Fingerprint

Amorphous films
Crystallization
Synchrotron radiation
synchrotron radiation
Irradiation
crystallization
Thin films
irradiation
Vacuum
vacuum
Crystals
crystals
Heating
heating
Crystal growth
excitation
Ionization
crystal growth
Electron beams
Mirrors

Keywords

  • Amorphous thin film
  • Crystallization
  • Electron microscopy
  • Irradiation
  • Tungsten oxide

ASJC Scopus subject areas

  • Surfaces, Coatings and Films
  • Instrumentation
  • Surfaces and Interfaces

Cite this

Irradiation effect of synchrotron radiation on crystallization of thin amorphous WO3 film. / Kimura, Yuki; Hanamoto, Katsumi; Nakayama, Yasuyuki; Kaito, Chihiro.

In: Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, Vol. 194, No. 2, 08.2002, p. 187-192.

Research output: Contribution to journalArticle

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