Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate

Yoichiro Kuninobu, Mitsumi Nishi, Kazuhiko Takai

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.

Original languageEnglish
Pages (from-to)8860-8862
Number of pages3
JournalChemical Communications
Volume46
Issue number46
DOIs
Publication statusPublished - Dec 14 2010

Fingerprint

Glycine
Amines
Amino acids
Nitrogen
Carbon
Iron
Derivatives
Ethanol
Salts
single bond

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate. / Kuninobu, Yoichiro; Nishi, Mitsumi; Takai, Kazuhiko.

In: Chemical Communications, Vol. 46, No. 46, 14.12.2010, p. 8860-8862.

Research output: Contribution to journalArticle

@article{c9aef2676f02438a8293518235e5c7f3,
title = "Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate",
abstract = "Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.",
author = "Yoichiro Kuninobu and Mitsumi Nishi and Kazuhiko Takai",
year = "2010",
month = "12",
day = "14",
doi = "10.1039/c0cc03781h",
language = "English",
volume = "46",
pages = "8860--8862",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "46",

}

TY - JOUR

T1 - Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate

AU - Kuninobu, Yoichiro

AU - Nishi, Mitsumi

AU - Takai, Kazuhiko

PY - 2010/12/14

Y1 - 2010/12/14

N2 - Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.

AB - Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.

UR - http://www.scopus.com/inward/record.url?scp=78549240207&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78549240207&partnerID=8YFLogxK

U2 - 10.1039/c0cc03781h

DO - 10.1039/c0cc03781h

M3 - Article

C2 - 20967333

AN - SCOPUS:78549240207

VL - 46

SP - 8860

EP - 8862

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 46

ER -