Abstract
β-1,3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions between 1,3-dicarbonyl compounds and two molecules of tertiary amines in the presence of tert-butyl hydroperoxide (TBHP). α,β-Unsaturated aldehydes generated by tertiary amine oxidation in situ act as key intermediates under mild reaction conditions.
Original language | English |
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Pages (from-to) | 6272-6275 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 13 |
Issue number | 23 |
DOIs | |
Publication status | Published - Dec 2 2011 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry