Abstract
Dehydrogenative dimerization of benzylmethylsilanes under iridium catalysis via site-selective sequential silylations of a C(sp3)H bond of the methyl group and ortho C(sp2)H bond of the benzyl group is described. Silicon-containing heterocycles were obtained in a single step from readily available functionalized benzylmethylsilanes.
| Original language | English |
|---|---|
| Pages (from-to) | 1044-1047 |
| Number of pages | 4 |
| Journal | Chemistry Letters |
| Volume | 46 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2017 |
Fingerprint
Keywords
- C-H activation
- Dehydrogenative silylation
- Iridium catalyst
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Iridium-catalyzed dehydrogenative dimerization of benzylmethylsilanes via silylation of C(sp3)H bonds adjacent to a silicon atom. / Murai, Masahito; Takeuchi, Yutaro; Takai, Kazuhiko.
In: Chemistry Letters, Vol. 46, No. 7, 2017, p. 1044-1047.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Iridium-catalyzed dehydrogenative dimerization of benzylmethylsilanes via silylation of C(sp3)H bonds adjacent to a silicon atom
AU - Murai, Masahito
AU - Takeuchi, Yutaro
AU - Takai, Kazuhiko
PY - 2017
Y1 - 2017
N2 - Dehydrogenative dimerization of benzylmethylsilanes under iridium catalysis via site-selective sequential silylations of a C(sp3)H bond of the methyl group and ortho C(sp2)H bond of the benzyl group is described. Silicon-containing heterocycles were obtained in a single step from readily available functionalized benzylmethylsilanes.
AB - Dehydrogenative dimerization of benzylmethylsilanes under iridium catalysis via site-selective sequential silylations of a C(sp3)H bond of the methyl group and ortho C(sp2)H bond of the benzyl group is described. Silicon-containing heterocycles were obtained in a single step from readily available functionalized benzylmethylsilanes.
KW - C-H activation
KW - Dehydrogenative silylation
KW - Iridium catalyst
UR - http://www.scopus.com/inward/record.url?scp=85021149470&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85021149470&partnerID=8YFLogxK
U2 - 10.1246/cl.170369
DO - 10.1246/cl.170369
M3 - Article
AN - SCOPUS:85021149470
VL - 46
SP - 1044
EP - 1047
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 7
ER -