Iridium-catalyzed dehydrogenative dimerization of benzylmethylsilanes via silylation of C(sp3)H bonds adjacent to a silicon atom

Masahito Murai; Yutaro Takeuchi; Kazuhiko Takai

doi:10.1246/cl.170369

Iridium-catalyzed dehydrogenative dimerization of benzylmethylsilanes via silylation of C(sp3)H bonds adjacent to a silicon atom

Masahito Murai, Yutaro Takeuchi, Kazuhiko Takai

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

Dehydrogenative dimerization of benzylmethylsilanes under iridium catalysis via site-selective sequential silylations of a C(sp³)H bond of the methyl group and ortho C(sp²)H bond of the benzyl group is described. Silicon-containing heterocycles were obtained in a single step from readily available functionalized benzylmethylsilanes.

Original language	English
Pages (from-to)	1044-1047
Number of pages	4
Journal	Chemistry Letters
Volume	46
Issue number	7
DOIs	https://doi.org/10.1246/cl.170369
Publication status	Published - 2017

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Keywords

C-H activation
Dehydrogenative silylation
Iridium catalyst

ASJC Scopus subject areas

Chemistry(all)

Cite this

Murai, M., Takeuchi, Y., & Takai, K. (2017). Iridium-catalyzed dehydrogenative dimerization of benzylmethylsilanes via silylation of C(sp3)H bonds adjacent to a silicon atom. Chemistry Letters, 46(7), 1044-1047. https://doi.org/10.1246/cl.170369

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Access to Document

10.1246/cl.170369