Iridium-catalysed hydrosilylation of cyclopropanes

Via regioselective carbon-carbon bond cleavage

Masahito Murai, Atsushi Nishiyama, Naoki Nishinaka, Haruka Morita, Kazuhiko Takai

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

While cyclopropanes have been explored as synthetically valuable building blocks, their transformation without conjugated substituents or directly substituted heteroatoms remains challenging. The current study describes the iridium-catalysed ring-opening hydrosilylation of cyclopropanes. A nitrogen-based directing group was found to control the reactivity of iridium active species as well as the regiochemistry of carbon-carbon bond cleavage and hydrosilylation.

Original languageEnglish
Pages (from-to)9281-9284
Number of pages4
JournalChemical Communications
Volume53
Issue number66
DOIs
Publication statusPublished - 2017

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Cyclopropanes
Hydrosilylation
Iridium
Carbon
Nitrogen

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Iridium-catalysed hydrosilylation of cyclopropanes : Via regioselective carbon-carbon bond cleavage. / Murai, Masahito; Nishiyama, Atsushi; Nishinaka, Naoki; Morita, Haruka; Takai, Kazuhiko.

In: Chemical Communications, Vol. 53, No. 66, 2017, p. 9281-9284.

Research output: Contribution to journalArticle

Murai, Masahito ; Nishiyama, Atsushi ; Nishinaka, Naoki ; Morita, Haruka ; Takai, Kazuhiko. / Iridium-catalysed hydrosilylation of cyclopropanes : Via regioselective carbon-carbon bond cleavage. In: Chemical Communications. 2017 ; Vol. 53, No. 66. pp. 9281-9284.
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