Intramolecular reaction of γ-alkoxyallylstannane with hydrazone: Stereoselective synthesis of β-aminotetrahydro-pyran and -furan

Isao Kadota, Jung Youl Park, Yoshinori Yamamoto

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The Lewis acid mediated cyclization of γ-oxygen substituted allylic stannanes 1, 2 and 9, bearing a hydrazone group at the terminus of the carbon chain, afforded the corresponding trans-β-amino cyclic ethers 3a, 4a and 10, respectively, with very high diastereoselectivities in high chemical yields.

Original languageEnglish
Pages (from-to)841-842
Number of pages2
JournalChemical Communications
Issue number7
Publication statusPublished - 1996
Externally publishedYes

Fingerprint

Bearings (structural)
Cyclic Ethers
Pyrans
Hydrazones
Lewis Acids
Cyclization
Ethers
Carbon
Oxygen
Acids
stannane
furan

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Intramolecular reaction of γ-alkoxyallylstannane with hydrazone : Stereoselective synthesis of β-aminotetrahydro-pyran and -furan. / Kadota, Isao; Park, Jung Youl; Yamamoto, Yoshinori.

In: Chemical Communications, No. 7, 1996, p. 841-842.

Research output: Contribution to journalArticle

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