Intramolecular participation in alkoxycarbenium ion pools

Seiji Suga, Shinkiti Suzuki, Jun Ichi Yoshida

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

(Chemical Equation Presented) Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as "cation pools" by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions.

Original languageEnglish
Pages (from-to)4717-4720
Number of pages4
JournalOrganic Letters
Volume7
Issue number21
DOIs
Publication statusPublished - Oct 13 2005
Externally publishedYes

Fingerprint

Ether
ethers
Ions
Cations
ions
Carbon
Stabilization
stabilization
Oxygen
cations
carbon
oxygen

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Intramolecular participation in alkoxycarbenium ion pools. / Suga, Seiji; Suzuki, Shinkiti; Yoshida, Jun Ichi.

In: Organic Letters, Vol. 7, No. 21, 13.10.2005, p. 4717-4720.

Research output: Contribution to journalArticle

Suga, Seiji ; Suzuki, Shinkiti ; Yoshida, Jun Ichi. / Intramolecular participation in alkoxycarbenium ion pools. In: Organic Letters. 2005 ; Vol. 7, No. 21. pp. 4717-4720.
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