Intramolecular nucleophilic addition of an organorhodium(I) to a nitrile

Tomoya Miura, Hiroki Nakazawa, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

59 Citations (Scopus)

Abstract

Nucleophilic addition of an organorhodium(I) to a cyano group has been observed for the first time in the rhodium-catalysed reaction of cyano-substituted alkynes with arylboronic acids. The higher reactivity of a cyano group relative to an alkoxycarbonyl group toward an organorhodium(I) species is demonstrated by an intramolecular example.

Original languageEnglish
Pages (from-to)2855-2856
Number of pages2
JournalChemical Communications
Issue number22
DOIs
Publication statusPublished - Jun 14 2005
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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