Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

Tomoya Miura, Yuuta Funakoshi, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

185 Citations (Scopus)

Abstract

The rhodium-catalyzed dearomatizing [3 + 2] annulation reaction of 4-(3-arylpropyl)-1,2,3-triazoles is described. It provides a straightforward synthetic pathway from simple 5-aryl-1-alkynes leading to tricyclic 3,4-fused dihydroindoles via the corresponding 1,2,3-triazoles.

Original languageEnglish
Pages (from-to)2272-2275
Number of pages4
JournalJournal of the American Chemical Society
Volume136
Issue number6
DOIs
Publication statusPublished - Feb 12 2014
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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