Internal flows in microscopic polymer solution droplets evaporating on flat surfaces

Shohei Yasumatsu, Narumi Nanri, Yu Yoshitake, Koichi Nakaso, Jun Fukai

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

To control the formation process of polymer thin films from polymer solution droplets using inkjet printings, internal flows of the droplets on substrates are studied. In our previous study [1], internal flow of polymer solution droplets receding on a lyophobic surface was experimentally visualized. It was found that the direction of the circulation flow in the droplet depended on the solvent and the initial solute concentration. In particular, the flow direction of polystyrene-anisole solution was reversed as the initial solute concentration increased. In this study, to clarify this reason, the conservation equations of momentum, energy and mass on two-dimensional cylindrical coordinate are numerically solved using a finite element method. The mathematical model considers the free convections derived by the dependencies of the density and surface tension on the solute concentration. As a result, the dependences of the calculated velocities on the initial solute concentration agree qualitatively with the experiments. The mathematical model predicts that double circulation flows appear after a single flow develops at high initial solute concentrations, while double circulations do not develop at low concentrations. It is concluded that the difference between the flow directions investigated experimentally is due to such a change of the flow structure. The distribution of the surface tension on the free surface is also discussed. When a local minimum of the surface tension appears on the free surface, the double circulations develop. According to the result for a low contact angle, the local minimum point shifts toward the axis of symmetry with a lapse of time, and finally erases the double circulations.

Original languageEnglish
Title of host publication2010 14th International Heat Transfer Conference, IHTC 14
Pages861-869
Number of pages9
Volume3
DOIs
Publication statusPublished - 2010
Externally publishedYes
Event2010 14th International Heat Transfer Conference, IHTC 14 - Washington, DC, United States
Duration: Aug 8 2010Aug 13 2010

Other

Other2010 14th International Heat Transfer Conference, IHTC 14
CountryUnited States
CityWashington, DC
Period8/8/108/13/10

Fingerprint

Polymer solutions
Surface tension
Mathematical models
Polystyrenes
Flow structure
Natural convection
Polymer films
Contact angle
Printing
Conservation
Momentum
Finite element method
Thin films
Substrates
Direction compound
Experiments

ASJC Scopus subject areas

  • Fluid Flow and Transfer Processes

Cite this

Yasumatsu, S., Nanri, N., Yoshitake, Y., Nakaso, K., & Fukai, J. (2010). Internal flows in microscopic polymer solution droplets evaporating on flat surfaces. In 2010 14th International Heat Transfer Conference, IHTC 14 (Vol. 3, pp. 861-869) https://doi.org/10.1115/IHTC14-23178

Internal flows in microscopic polymer solution droplets evaporating on flat surfaces. / Yasumatsu, Shohei; Nanri, Narumi; Yoshitake, Yu; Nakaso, Koichi; Fukai, Jun.

2010 14th International Heat Transfer Conference, IHTC 14. Vol. 3 2010. p. 861-869.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Yasumatsu, S, Nanri, N, Yoshitake, Y, Nakaso, K & Fukai, J 2010, Internal flows in microscopic polymer solution droplets evaporating on flat surfaces. in 2010 14th International Heat Transfer Conference, IHTC 14. vol. 3, pp. 861-869, 2010 14th International Heat Transfer Conference, IHTC 14, Washington, DC, United States, 8/8/10. https://doi.org/10.1115/IHTC14-23178
Yasumatsu S, Nanri N, Yoshitake Y, Nakaso K, Fukai J. Internal flows in microscopic polymer solution droplets evaporating on flat surfaces. In 2010 14th International Heat Transfer Conference, IHTC 14. Vol. 3. 2010. p. 861-869 https://doi.org/10.1115/IHTC14-23178
Yasumatsu, Shohei ; Nanri, Narumi ; Yoshitake, Yu ; Nakaso, Koichi ; Fukai, Jun. / Internal flows in microscopic polymer solution droplets evaporating on flat surfaces. 2010 14th International Heat Transfer Conference, IHTC 14. Vol. 3 2010. pp. 861-869
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