Abstract
Presence of an unique atom-to-face alcoholic oxygen atom⋯π interaction between a pentafluorophenyl group and alcoholic oxygen (O⋯π) has been demonstrated by X-ray analysis of the novel chiral amino alcohol instead of the well-known interaction between usual aromatic ring and alcoholic hydrogen atom (OH⋯π).
| Original language | English |
|---|---|
| Pages (from-to) | 201-205 |
| Number of pages | 5 |
| Journal | Journal of Fluorine Chemistry |
| Volume | 122 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Aug 1 2003 |
Keywords
- Amino alcohol
- Aromatic interaction
- Asymmetric synthesis
- Attractive interaction
- Chiral ligand
ASJC Scopus subject areas
- Biochemistry
- Environmental Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Cite this
Korenaga, T., Tanaka, H., Ema, T., & Sakai, T. (2003). Intermolecular oxygen atom⋯π interaction in the crystal packing of chiral amino alcohol bearing a pentafluorophenyl group. Journal of Fluorine Chemistry, 122(2), 201-205. https://doi.org/10.1016/S0022-1139(03)00089-7