Intermolecular oxygen atom⋯π interaction in the crystal packing of chiral amino alcohol bearing a pentafluorophenyl group

Toshinobu Korenaga, Hikaru Tanaka, Tadashi Ema, Takashi Sakai

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Presence of an unique atom-to-face alcoholic oxygen atom⋯π interaction between a pentafluorophenyl group and alcoholic oxygen (O⋯π) has been demonstrated by X-ray analysis of the novel chiral amino alcohol instead of the well-known interaction between usual aromatic ring and alcoholic hydrogen atom (OH⋯π).

Original languageEnglish
Pages (from-to)201-205
Number of pages5
JournalJournal of Fluorine Chemistry
Volume122
Issue number2
DOIs
Publication statusPublished - Aug 1 2003

Keywords

  • Amino alcohol
  • Aromatic interaction
  • Asymmetric synthesis
  • Attractive interaction
  • Chiral ligand

ASJC Scopus subject areas

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Intermolecular oxygen atom⋯π interaction in the crystal packing of chiral amino alcohol bearing a pentafluorophenyl group'. Together they form a unique fingerprint.

  • Cite this