Infrared spectra of seeded hydrogen clusters: (paraH2) N-OCS, (orthoH2)N-OCS, and (HD) N-OCS, N=2-7

J. Tang, A. R.W. McKellar

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

The infrared spectra of hydrogen-carbonyl sulfide clusters containing paraH2, orthoH2 or HD were investigated in the 2060 cm-1 region of C-O stretching vibration. A tunable infrared diode laser spectrometer was used for the formation of these clusters in pulsed supersonic jet expansions. Some mixed clusters such as HD-HD-He-OCS and paraH2-orthoH2-OCS were also observed. The results show that the observed rotational structure corresponds to that of simple symmetric rotors, with prominent Q branches for the orthoH2 and HD clusters.

Original languageEnglish
Pages (from-to)3087-3095
Number of pages9
JournalJournal of Chemical Physics
Volume121
Issue number7
DOIs
Publication statusPublished - Aug 15 2004
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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