Infrared spectra of OCS-hydrogen complexes

Jian Tang, A. R.W. McKellar

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Infrared spectroscopy was used to analyze OCS-hydrogen van der Waals complexes in the region of vibrational bands. Five distinct species of the complex were observed in a pulsed supersonic jet expansion using a tunable diode laser probe. Results indicated that the band origins were red-shifted relative to the free OCS molecule. The fitted rotational parameters were found to be consistent with the structures having intermolecular separations in the range of 3.6 Å-3.8 Å.

Original languageEnglish
Pages (from-to)646-653
Number of pages8
JournalJournal of Chemical Physics
Volume116
Issue number2
DOIs
Publication statusPublished - Jan 8 2002

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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