Infrared spectra of N2O-hydrogen complexes

Jian Tang, A. R.W. McKellar

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.

Original languageEnglish
Pages (from-to)8308-8313
Number of pages6
JournalJournal of Chemical Physics
Volume117
Issue number18
DOIs
Publication statusPublished - Nov 8 2002
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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