Infrared spectra of N2O-hydrogen complexes

Jian Tang, A. R W McKellar

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.

Original languageEnglish
Pages (from-to)8308-8313
Number of pages6
JournalThe Journal of Chemical Physics
Volume117
Issue number18
DOIs
Publication statusPublished - Nov 8 2002
Externally publishedYes

Fingerprint

Hydrogen
infrared spectra
Infrared radiation
Hamiltonians
hydrogen
rotors
Rotors

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Infrared spectra of N2O-hydrogen complexes. / Tang, Jian; McKellar, A. R W.

In: The Journal of Chemical Physics, Vol. 117, No. 18, 08.11.2002, p. 8308-8313.

Research output: Contribution to journalArticle

Tang, Jian ; McKellar, A. R W. / Infrared spectra of N2O-hydrogen complexes. In: The Journal of Chemical Physics. 2002 ; Vol. 117, No. 18. pp. 8308-8313.
@article{345b4e256c1f41598c459026158d4a82,
title = "Infrared spectra of N2O-hydrogen complexes",
abstract = "Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.",
author = "Jian Tang and McKellar, {A. R W}",
year = "2002",
month = "11",
day = "8",
doi = "10.1063/1.1514207",
language = "English",
volume = "117",
pages = "8308--8313",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "18",

}

TY - JOUR

T1 - Infrared spectra of N2O-hydrogen complexes

AU - Tang, Jian

AU - McKellar, A. R W

PY - 2002/11/8

Y1 - 2002/11/8

N2 - Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.

AB - Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.

UR - http://www.scopus.com/inward/record.url?scp=0037044974&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037044974&partnerID=8YFLogxK

U2 - 10.1063/1.1514207

DO - 10.1063/1.1514207

M3 - Article

VL - 117

SP - 8308

EP - 8313

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 18

ER -