Infrared Spectra of Bis(L-serinato)nickel(H) Dihydrate by Using Metal Isotope Technique

Junichi Odo, Masaki Mifune, Akimasa Iwado, Yutaka Saito, Yoshimasa Tanaka, Noriko Motohashi, Katsunosuke Machida

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The infrared spectra of bis(L-serinato)nickel(II) dihydrate (Ni(L-ser)2 • 2H20) and their isotopic complexes containing 58Ni, 62Ni and deuterium have been measured in the region between 4000 and 200 cm1. The shifts caused by nickel and hydrogen isotopic substitutions indicate that three bands at 342,297 and 222 cm “1 are Ni-ligand stretching vibrations complicatedly coupled with Ni-O and Ni-N stretching vibrations. The conformational differences between gauche-anti and anti-gauche serinates in metallo-serinate complexes are characterized by the COO deformation vibrations. A normal coordinate analysis on the basis of a complete molecular conformation of Ni(L-ser)2 • 2H20 and an intermolecular force field reproduced well the observed frequencies and isotope shifts. In addition, the calculated result is consistent with both the empirical assignments and the observed frequency differences caused from the conformational differences.

Original languageEnglish
Pages (from-to)247-250
Number of pages4
JournalChemical and Pharmaceutical Bulletin
Volume39
Issue number2
DOIs
Publication statusPublished - 1991

Keywords

  • L-serine
  • Ni-Ni substitution
  • bis(L-serinato)nickel(II) dihydrate
  • conformational difference
  • deuteration
  • infrared spectra
  • intermolecular force
  • intramolecular force
  • normal coordinate analysis

ASJC Scopus subject areas

  • Chemistry(all)
  • Drug Discovery

Fingerprint Dive into the research topics of 'Infrared Spectra of Bis(L-serinato)nickel(H) Dihydrate by Using Metal Isotope Technique'. Together they form a unique fingerprint.

Cite this