Infrared diode laser spectroscopy of the v1 fundamental and v1 + v5 - v5 bands of the C3S molecule

Shuro Takano; Jian Tang; Shuji Saito

doi:10.1006/jmsp.1996.0174

Infrared diode laser spectroscopy of the v₁ fundamental and v₁ + v₅ - v₅ bands of the C₃S molecule

Shuro Takano, Jian Tang, Shuji Saito

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The vibration-rotation absorption spectra of the C₃S molecule were studied using a tunable infrared diode laser spectrometer. The v₁ fundamental and v₁ + v₅ - v₅ hot bands were measured between 2046 and 2067 cm^-1. The C₃S molecule was produced by a glow discharge in a flowing mixture of CS₂, C₂H₂, and He. The analysis of the measured spectral lines yielded the band origins, the rotational and centrifugal distortion constants in the upper vibrational states, and the l-type doubling constant for the v₁ + v₅ state. The band origins were determined to be 2058.21875(47) and 2053.03769(45) cm^-1 for the v₁ fundamental and v₁ + v₅ - v₅ bands, respectively. The values in the parentheses correspond to three standard deviations.

Original language	English
Pages (from-to)	194-198
Number of pages	5
Journal	Journal of Molecular Spectroscopy
Volume	178
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.1996.0174
Publication status	Published - Aug 1996
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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10.1006/jmsp.1996.0174

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title = "Infrared diode laser spectroscopy of the v1 fundamental and v1 + v5 - v5 bands of the C3S molecule",

abstract = "The vibration-rotation absorption spectra of the C3S molecule were studied using a tunable infrared diode laser spectrometer. The v1 fundamental and v1 + v5 - v5 hot bands were measured between 2046 and 2067 cm-1. The C3S molecule was produced by a glow discharge in a flowing mixture of CS2, C2H2, and He. The analysis of the measured spectral lines yielded the band origins, the rotational and centrifugal distortion constants in the upper vibrational states, and the l-type doubling constant for the v1 + v5 state. The band origins were determined to be 2058.21875(47) and 2053.03769(45) cm-1 for the v1 fundamental and v1 + v5 - v5 bands, respectively. The values in the parentheses correspond to three standard deviations.",

author = "Shuro Takano and Jian Tang and Shuji Saito",

year = "1996",

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T1 - Infrared diode laser spectroscopy of the v1 fundamental and v1 + v5 - v5 bands of the C3S molecule

AU - Takano, Shuro

AU - Tang, Jian

AU - Saito, Shuji

PY - 1996/8

Y1 - 1996/8

N2 - The vibration-rotation absorption spectra of the C3S molecule were studied using a tunable infrared diode laser spectrometer. The v1 fundamental and v1 + v5 - v5 hot bands were measured between 2046 and 2067 cm-1. The C3S molecule was produced by a glow discharge in a flowing mixture of CS2, C2H2, and He. The analysis of the measured spectral lines yielded the band origins, the rotational and centrifugal distortion constants in the upper vibrational states, and the l-type doubling constant for the v1 + v5 state. The band origins were determined to be 2058.21875(47) and 2053.03769(45) cm-1 for the v1 fundamental and v1 + v5 - v5 bands, respectively. The values in the parentheses correspond to three standard deviations.

AB - The vibration-rotation absorption spectra of the C3S molecule were studied using a tunable infrared diode laser spectrometer. The v1 fundamental and v1 + v5 - v5 hot bands were measured between 2046 and 2067 cm-1. The C3S molecule was produced by a glow discharge in a flowing mixture of CS2, C2H2, and He. The analysis of the measured spectral lines yielded the band origins, the rotational and centrifugal distortion constants in the upper vibrational states, and the l-type doubling constant for the v1 + v5 state. The band origins were determined to be 2058.21875(47) and 2053.03769(45) cm-1 for the v1 fundamental and v1 + v5 - v5 bands, respectively. The values in the parentheses correspond to three standard deviations.

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Infrared diode laser spectroscopy of the v₁ fundamental and v₁ + v₅ - v₅ bands of the C₃S molecule

Abstract

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