Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

Qiu Jian Rong, Akiyoshi Osaka, Tokuro Nanba, Jun Takada, Yoshinari Miura

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO3 -units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.

Original languageEnglish
Pages (from-to)3793-3798
Number of pages6
JournalJournal of Materials Science
Volume27
Issue number14
DOIs
Publication statusPublished - Jan 1992

Fingerprint

boron oxides
indium oxides
Indium
Boron
Raman scattering
infrared spectra
Raman spectra
Infrared radiation
Glass
Oxides
glass
constitution
Raman spectroscopy
Infrared spectroscopy
oxygen atoms
infrared spectroscopy
Oxygen
Atoms
configurations
indium oxide

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials
  • Materials Science(all)

Cite this

Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides. / Rong, Qiu Jian; Osaka, Akiyoshi; Nanba, Tokuro; Takada, Jun; Miura, Yoshinari.

In: Journal of Materials Science, Vol. 27, No. 14, 01.1992, p. 3793-3798.

Research output: Contribution to journalArticle

Rong, Qiu Jian ; Osaka, Akiyoshi ; Nanba, Tokuro ; Takada, Jun ; Miura, Yoshinari. / Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides. In: Journal of Materials Science. 1992 ; Vol. 27, No. 14. pp. 3793-3798.
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