Infrared absorption spectra of SiF4 and its clusters in solid parahydrogen

Hiroki Ooe, Yuki Miyamoto, Susumu Kuma, Noboru Sasao, Kentarou Kawaguchi

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We observed infrared absorption spectra of tetrahedral silicon tetrafluoride (SiF4) and its clusters in solid parahydrogen. The spectra were assigned by a temporal change of the peak intensity with annealing and previous studies in the gas and other matrices. It was found that the SiF4 monomer does not rotate in solid parahydrogen in spite of its small size and the absence of the permanent electric dipole moment. The dimer spectra are similar to those in the gas phase except for complicated sub-structures. Some other peaks were tentatively assigned to trimer and larger clusters. Clusters with other impurities were also observed.

Original languageEnglish
Pages (from-to)54-58
Number of pages5
JournalChemical Physics Letters
Volume631-632
DOIs
Publication statusPublished - May 17 2015

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Infrared absorption
infrared absorption
Absorption spectra
infrared spectra
absorption spectra
Gases
Electric dipole moments
electric moments
trimers
Dimers
electric dipoles
dipole moments
monomers
Monomers
dimers
Annealing
Impurities
vapor phases
impurities
annealing

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Physics and Astronomy(all)

Cite this

Infrared absorption spectra of SiF4 and its clusters in solid parahydrogen. / Ooe, Hiroki; Miyamoto, Yuki; Kuma, Susumu; Sasao, Noboru; Kawaguchi, Kentarou.

In: Chemical Physics Letters, Vol. 631-632, 17.05.2015, p. 54-58.

Research output: Contribution to journalArticle

Ooe, Hiroki ; Miyamoto, Yuki ; Kuma, Susumu ; Sasao, Noboru ; Kawaguchi, Kentarou. / Infrared absorption spectra of SiF4 and its clusters in solid parahydrogen. In: Chemical Physics Letters. 2015 ; Vol. 631-632. pp. 54-58.
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