Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai; Yoshito Ikawa

doi:10.1021/ol025784v

Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai, Yoshito Ikawa

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

Original language	English
Pages (from-to)	1727-1729
Number of pages	3
Journal	Organic Letters
Volume	4
Issue number	10
DOIs	https://doi.org/10.1021/ol025784v
Publication status	Published - May 16 2002
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol025784v

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title = "Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides",

abstract = "Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.",

author = "Kazuhiko Takai and Yoshito Ikawa",

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AU - Takai, Kazuhiko

AU - Ikawa, Yoshito

PY - 2002/5/16

Y1 - 2002/5/16

N2 - Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

AB - Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

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Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Abstract

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