Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai; Yoshito Ikawa

doi:10.1021/ol025784v

Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai, Yoshito Ikawa

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

Original language	English
Pages (from-to)	1727-1729
Number of pages	3
Journal	Organic Letters
Volume	4
Issue number	10
DOIs	https://doi.org/10.1021/ol025784v
Publication status	Published - May 16 2002

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol025784v

Cite this

@article{1cde7ec767614a1db3e6365fee79a5eb,

title = "Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides",

abstract = "Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.",

author = "Kazuhiko Takai and Yoshito Ikawa",

year = "2002",

month = may,

day = "16",

doi = "10.1021/ol025784v",

language = "English",

volume = "4",

pages = "1727--1729",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

AU - Takai, Kazuhiko

AU - Ikawa, Yoshito

PY - 2002/5/16

Y1 - 2002/5/16

N2 - Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

AB - Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

UR - http://www.scopus.com/inward/record.url?scp=0000168812&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000168812&partnerID=8YFLogxK

U2 - 10.1021/ol025784v

DO - 10.1021/ol025784v

M3 - Article

C2 - 12000284

AN - SCOPUS:0000168812

VL - 4

SP - 1727

EP - 1729

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 10

ER -

Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this