Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai, Yoshito Ikawa

Research output: Contribution to journal › Article

59 Citations (Scopus)

Abstract

Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

Original languageEnglish
Pages (from-to)1727-1729
Number of pages3
JournalOrganic Letters
Volume4
Issue number10
DOIs
Publication statusPublished - May 16 2002

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Gallium
Indium
Aluminum
gallium
indium
bromides
aluminum
Catalysis
catalysis
assembly
Metals
cycles
matrices
metals
allyl bromide

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides. / Takai, Kazuhiko; Ikawa, Yoshito.

In: Organic Letters, Vol. 4, No. 10, 16.05.2002, p. 1727-1729.

Research output: Contribution to journal › Article

Takai, K & Ikawa, Y 2002, 'Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides', Organic Letters, vol. 4, no. 10, pp. 1727-1729. https://doi.org/10.1021/ol025784v
Takai K, Ikawa Y. Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides. Organic Letters. 2002 May 16;4(10):1727-1729. https://doi.org/10.1021/ol025784v
Takai, Kazuhiko ; Ikawa, Yoshito. / Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides. In: Organic Letters. 2002 ; Vol. 4, No. 10. pp. 1727-1729.
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