Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai; Yoshito Ikawa

doi:10.1021/ol025784v

Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai, Yoshito Ikawa

Research output: Contribution to journal › Article

61 Citations (Scopus)

Abstract

Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

Original language	English
Pages (from-to)	1727-1729
Number of pages	3
Journal	Organic Letters
Volume	4
Issue number	10
DOIs	https://doi.org/10.1021/ol025784v
Publication status	Published - May 16 2002

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol025784v

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Takai, K., & Ikawa, Y. (2002). Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides. Organic Letters, 4(10), 1727-1729. https://doi.org/10.1021/ol025784v

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abstract = "Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.",

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AB - Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

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