Indirect cation-flow method: Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations

Kodai Saito, Koji Ueoka, Kouichi Matsumoto, Seiji Suga, Toshiki Nokami, Jun Ichi Yoshida

    Research output: Contribution to journalArticlepeer-review

    63 Citations (Scopus)

    Abstract

    Go with the flow: The indirect cation-flow method based on the generation of highly reactive organic cations from their precursors using electrochemically generated [ArS(ArSSAr)]+ was developed in flow microreactor systems (see scheme; Bn=benzyl, M=micromixer, R=microtube reactor). The method was applied to evaluate glycosyl cations such as A or their equivalents and glycosylation reactions.

    Original languageEnglish
    Pages (from-to)5153-5156
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume50
    Issue number22
    DOIs
    Publication statusPublished - May 23 2011

    Keywords

    • carbohydrates
    • cations
    • electrochemistry
    • microreactors
    • sulfur

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)

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