Indirect cation-flow method

Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations

Kodai Saito, Koji Ueoka, Kouichi Matsumoto, Seiji Suga, Toshiki Nokami, Jun Ichi Yoshida

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Go with the flow: The indirect cation-flow method based on the generation of highly reactive organic cations from their precursors using electrochemically generated [ArS(ArSSAr)]+ was developed in flow microreactor systems (see scheme; Bn=benzyl, M=micromixer, R=microtube reactor). The method was applied to evaluate glycosyl cations such as A or their equivalents and glycosylation reactions.

Original languageEnglish
Pages (from-to)5153-5156
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number22
DOIs
Publication statusPublished - May 23 2011

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Cations
Positive ions
Ions
Glycosylation

Keywords

  • carbohydrates
  • cations
  • electrochemistry
  • microreactors
  • sulfur

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Indirect cation-flow method : Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations. / Saito, Kodai; Ueoka, Koji; Matsumoto, Kouichi; Suga, Seiji; Nokami, Toshiki; Yoshida, Jun Ichi.

In: Angewandte Chemie - International Edition, Vol. 50, No. 22, 23.05.2011, p. 5153-5156.

Research output: Contribution to journalArticle

Saito, Kodai ; Ueoka, Koji ; Matsumoto, Kouichi ; Suga, Seiji ; Nokami, Toshiki ; Yoshida, Jun Ichi. / Indirect cation-flow method : Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations. In: Angewandte Chemie - International Edition. 2011 ; Vol. 50, No. 22. pp. 5153-5156.
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