In vitro apatite deposition on titania film derived from chemical treatment of Ti substrates with an oxysulfate solution containing hydrogen peroxide at low temperature

Fan Xiao; Kanji Tsuru; Satoshi Hayakawa; Akiyoshi Osaka

doi:10.1016/S0040-6090(03)00913-1

In vitro apatite deposition on titania film derived from chemical treatment of Ti substrates with an oxysulfate solution containing hydrogen peroxide at low temperature

Fan Xiao, Kanji Tsuru, Satoshi Hayakawa, Akiyoshi Osaka

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

Thin titania film consisting of anatase and rutile was deposited on Ti substrates when soaked in a TiOSO₄/H₂O₂ solution and aged in hot water. H₂O₂ corroded the Ti substrates, yielded a porous surface, and kept the solution from peptization. Thicker titania layers were formed in favor of both a greater supersaturation of Ti(IV) in the solution and a higher concentration of hydrated Ti(IV) derived by the corrosion of Ti and the hydrolysis of TiOSO₄. The effects of aging in hot water were accounted for as they caused structural relaxation of the surface layer involving a rearrangement of Ti-OH and eliminating residual species like peroxide ions. Those titania layers were thus favored to deposit apatite when the Ti substrates were placed under a body environment, i.e. soaked in a simulated body fluid of Kokubo's recipe.

Original language	English
Pages (from-to)	271-276
Number of pages	6
Journal	Thin Solid Films
Volume	441
Issue number	1-2
DOIs	https://doi.org/10.1016/S0040-6090(03)00913-1
Publication status	Published - Sep 22 2003

Keywords

Apatite-forming ability
Hydrogen peroxide
Low temperature
Titania
Titanium oxysulfate

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Surfaces and Interfaces
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "In vitro apatite deposition on titania film derived from chemical treatment of Ti substrates with an oxysulfate solution containing hydrogen peroxide at low temperature",

abstract = "Thin titania film consisting of anatase and rutile was deposited on Ti substrates when soaked in a TiOSO4/H2O2 solution and aged in hot water. H2O2 corroded the Ti substrates, yielded a porous surface, and kept the solution from peptization. Thicker titania layers were formed in favor of both a greater supersaturation of Ti(IV) in the solution and a higher concentration of hydrated Ti(IV) derived by the corrosion of Ti and the hydrolysis of TiOSO4. The effects of aging in hot water were accounted for as they caused structural relaxation of the surface layer involving a rearrangement of Ti-OH and eliminating residual species like peroxide ions. Those titania layers were thus favored to deposit apatite when the Ti substrates were placed under a body environment, i.e. soaked in a simulated body fluid of Kokubo's recipe.",

keywords = "Apatite-forming ability, Hydrogen peroxide, Low temperature, Titania, Titanium oxysulfate",

author = "Fan Xiao and Kanji Tsuru and Satoshi Hayakawa and Akiyoshi Osaka",

note = "Funding Information: One of the authors (F. Xiao) gratefully acknowledges the financial support of the Heiwa Nakajima Foundation, Japan. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2003",

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doi = "10.1016/S0040-6090(03)00913-1",

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volume = "441",

pages = "271--276",

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T1 - In vitro apatite deposition on titania film derived from chemical treatment of Ti substrates with an oxysulfate solution containing hydrogen peroxide at low temperature

AU - Xiao, Fan

AU - Tsuru, Kanji

AU - Hayakawa, Satoshi

AU - Osaka, Akiyoshi

N1 - Funding Information: One of the authors (F. Xiao) gratefully acknowledges the financial support of the Heiwa Nakajima Foundation, Japan. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2003/9/22

Y1 - 2003/9/22

N2 - Thin titania film consisting of anatase and rutile was deposited on Ti substrates when soaked in a TiOSO4/H2O2 solution and aged in hot water. H2O2 corroded the Ti substrates, yielded a porous surface, and kept the solution from peptization. Thicker titania layers were formed in favor of both a greater supersaturation of Ti(IV) in the solution and a higher concentration of hydrated Ti(IV) derived by the corrosion of Ti and the hydrolysis of TiOSO4. The effects of aging in hot water were accounted for as they caused structural relaxation of the surface layer involving a rearrangement of Ti-OH and eliminating residual species like peroxide ions. Those titania layers were thus favored to deposit apatite when the Ti substrates were placed under a body environment, i.e. soaked in a simulated body fluid of Kokubo's recipe.

AB - Thin titania film consisting of anatase and rutile was deposited on Ti substrates when soaked in a TiOSO4/H2O2 solution and aged in hot water. H2O2 corroded the Ti substrates, yielded a porous surface, and kept the solution from peptization. Thicker titania layers were formed in favor of both a greater supersaturation of Ti(IV) in the solution and a higher concentration of hydrated Ti(IV) derived by the corrosion of Ti and the hydrolysis of TiOSO4. The effects of aging in hot water were accounted for as they caused structural relaxation of the surface layer involving a rearrangement of Ti-OH and eliminating residual species like peroxide ions. Those titania layers were thus favored to deposit apatite when the Ti substrates were placed under a body environment, i.e. soaked in a simulated body fluid of Kokubo's recipe.

KW - Apatite-forming ability

KW - Hydrogen peroxide

KW - Low temperature

KW - Titania

KW - Titanium oxysulfate

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U2 - 10.1016/S0040-6090(03)00913-1

DO - 10.1016/S0040-6090(03)00913-1

M3 - Article

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VL - 441

SP - 271

EP - 276

JO - Thin Solid Films

JF - Thin Solid Films

SN - 0040-6090

IS - 1-2

ER -

In vitro apatite deposition on titania film derived from chemical treatment of Ti substrates with an oxysulfate solution containing hydrogen peroxide at low temperature

Abstract

Keywords

ASJC Scopus subject areas

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