In situ XPS Spectra of Nonstoichiometric Fe3−δO4(100) Films

Tatsuo Fujii; Frans C. Voogt; Tjipke Hibma; George A. Sawatzky

doi:10.1116/1.1247938

In situ XPS Spectra of Nonstoichiometric Fe_3−δO₄(100) Films

Tatsuo Fujii, Frans C. Voogt, Tjipke Hibma, George A. Sawatzky

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

XPS core- and valence-level spectra of various nonstoichiometric Fe_3−δO₄ films were measured systematically as a function of the δ value. The films were prepared epitaxially on MgO(100) substrates by NO₂-assisted molecular beam epitaxy and characterized in situ with RHEED, LEED, and XPS. Stoichiometry of the films was controlled precisely by adjusting the NO₂ pressure during deposition and analyzed ex situ by conversion electron Mössbauer spectroscopy.

Original language	English
Pages (from-to)	337-346
Number of pages	10
Journal	Surface Science Spectra
Volume	6
Issue number	4
DOIs	https://doi.org/10.1116/1.1247938
Publication status	Published - Oct 1 1999
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films

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abstract = "XPS core- and valence-level spectra of various nonstoichiometric Fe3−δO4 films were measured systematically as a function of the δ value. The films were prepared epitaxially on MgO(100) substrates by NO2-assisted molecular beam epitaxy and characterized in situ with RHEED, LEED, and XPS. Stoichiometry of the films was controlled precisely by adjusting the NO2 pressure during deposition and analyzed ex situ by conversion electron M{\"o}ssbauer spectroscopy.",

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AU - Hibma, Tjipke

AU - Sawatzky, George A.

PY - 1999/10/1

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AB - XPS core- and valence-level spectra of various nonstoichiometric Fe3−δO4 films were measured systematically as a function of the δ value. The films were prepared epitaxially on MgO(100) substrates by NO2-assisted molecular beam epitaxy and characterized in situ with RHEED, LEED, and XPS. Stoichiometry of the films was controlled precisely by adjusting the NO2 pressure during deposition and analyzed ex situ by conversion electron Mössbauer spectroscopy.

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In situ XPS Spectra of Nonstoichiometric Fe_3−δO₄(100) Films

Abstract

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