TY - CHAP
T1 - In situ X-ray diffraction studies on micropore filling
AU - Iiyama, T.
AU - Ohkubo, T.
AU - Kaneko, K.
N1 - Funding Information:
This work was funded by the Grant in-Aid for Scientific Research on Priority Areas No. 288 "Carbon Alloys" from Japanese Government. We thank to Professor Keiko Nishikawa for her helpful discussion on ERDF analysis and Mr. Tomonori Ohba and Miss. Takako Kimura for their preparation of this manuscript.
Copyright:
Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2000
Y1 - 2000
N2 - The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl 4 , water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
AB - The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl 4 , water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
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U2 - 10.1016/S0927-5193(00)80004-2
DO - 10.1016/S0927-5193(00)80004-2
M3 - Chapter
AN - SCOPUS:77956959368
T3 - Membrane Science and Technology
SP - 35
EP - 66
BT - Membrane Science and Technology
PB - Elsevier
ER -