TY - CHAP
T1 - In situ X-ray diffraction studies on micropore filling
AU - Iiyama, T.
AU - Ohkubo, T.
AU - Kaneko, K.
PY - 2000/1/1
Y1 - 2000/1/1
N2 - The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl 4 , water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
AB - The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl 4 , water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
UR - http://www.scopus.com/inward/record.url?scp=77956959368&partnerID=8YFLogxK
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U2 - 10.1016/S0927-5193(00)80004-2
DO - 10.1016/S0927-5193(00)80004-2
M3 - Chapter
AN - SCOPUS:77956959368
T3 - Membrane Science and Technology
SP - 35
EP - 66
BT - Membrane Science and Technology
PB - Elsevier
ER -