Abstract
The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl4, water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
| Original language | English |
|---|---|
| Pages (from-to) | 35-66 |
| Number of pages | 32 |
| Journal | Membrane Science and Technology |
| Volume | 6 |
| Issue number | C |
| DOIs | |
| Publication status | Published - 2000 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Surfaces, Coatings and Films
- Chemical Engineering(all)
Cite this
In situ X-ray diffraction studies on micropore filling. / Iiyama, T.; Ohkubo, Takahiro; Kaneko, K.
In: Membrane Science and Technology, Vol. 6, No. C, 2000, p. 35-66.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - In situ X-ray diffraction studies on micropore filling
AU - Iiyama, T.
AU - Ohkubo, Takahiro
AU - Kaneko, K.
PY - 2000
Y1 - 2000
N2 - The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl4, water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
AB - The molecular level picture of micropore filling mechanism in carbon micropores was summarized and the necessity of the structural study on molecules confined in carbon micropores with in situ X-ray diffraction is described. The detailed explanation of in situ X-ray diffraction technique for adsorption studies is given. The effectiveness of the in situ X-ray diffraction for elucidation of structures of molecules filled in micropore is shown for CCl4, water, and alcohol molecules. In situ X-ray diffraction studies shows the presence of organized structure inherent to an adsorbate molecule, although only adsorption measurement cannot distinguish the molecular state different from the bulk liquid.
UR - http://www.scopus.com/inward/record.url?scp=77956959368&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77956959368&partnerID=8YFLogxK
U2 - 10.1016/S0927-5193(00)80004-2
DO - 10.1016/S0927-5193(00)80004-2
M3 - Article
AN - SCOPUS:77956959368
VL - 6
SP - 35
EP - 66
JO - Membrane Science and Technology
JF - Membrane Science and Technology
SN - 0927-5193
IS - C
ER -