In situ photolysis of CD3i in solid orthodeuterium

Mizuho Fushitani, Yuki Miyamoto, Hiromichi Hoshina, Takamasa Momose

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Photochemical reactions of molecules in solid orthodeuterium (o-D 2) have been studied by high-resolution infrared spectroscopy and compared with previous results obtained in solid parahydrogen (p-H2). Ultraviolet photolysis of CD3I molecules in solid o-D2 yielded CD3 radicals and iodine atoms efficiently, which indicates a small cage effect in solid o-D2, as in the case of solid p-H 2. The Fourier transform infrared spectrum of the ν3 vibrational band of CD3 showed a rotational structure with additional splitting due to crystal field interactions. The magnetic dipole transition (2P1/22P3/2) of the I atom isolated in solid o-D2 was observed together with a strong rotational satellite of deuterium molecules through the electron-roton coupling in solid hydrogen. The tunneling reaction between CD3 and D2 was not observed in a time scale of a few days, which gives the upper limit of the tunneling reaction rate of 10-8 s-1 at 4.2 K.

Original languageEnglish
Pages (from-to)12629-12634
Number of pages6
JournalJournal of Physical Chemistry A
Volume111
Issue number49
DOIs
Publication statusPublished - Dec 13 2007
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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