Hydrothermal synthesis of hexagonal vanadium oxide

T. Tokuyama, T. Okusako, K. Mikami, N. Hanasaki, Yoshio Nogami

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Abstract

We synthesize the hexagonal vanadium oxide containing the alkaline-metal ion (Li, Na, and K). The crystal belongs to the magnetoplumbite-type structure. The title compound, in which the vanadium valance is not an integer, shows the metallic and the paramagnetic behavior. The electronic specific heat coefficient γ is 34.7 mJ/K2mol, which is perhaps due to the spin fluctuation.

Original languageEnglish
Article number012073
JournalJournal of Physics: Conference Series
Volume320
DOIs
Publication statusPublished - 2011

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ASJC Scopus subject areas

  • Physics and Astronomy(all)

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