Hydrolase-catalyzed kinetic resolution of 5-[4-(1-hydroxyethyl)phenyl]-10, 15,20-tris(pentafluorophenyl)porphyrin in ionic liquids

Tadashi Ema, Tokuhiro Doi, Takashi Sakai

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Abstract

Bulky alcohol, 5-[4-(1-hydroxyethyl)phenyl]-10,15,20-tris- (pentafluorophenyl)porphyrin (1b), was synthesized, and enantiomerically pure alcohol 1b and ester 2b were obtained by a single kinetic resolution catalyzed by Candida antarctica lipase in i-Pr2O and in [bdmim] [PF 6].

Original languageEnglish
Pages (from-to)90-91
Number of pages2
JournalChemistry Letters
Volume37
Issue number1
DOIs
Publication statusPublished - Jan 5 2008

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ASJC Scopus subject areas

  • Chemistry(all)

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