Hydrolase-catalyzed kinetic resolution of 5-[4-(1-hydroxyethyl)phenyl]-10, 15,20-tris(pentafluorophenyl)porphyrin in ionic liquids

Tadashi Ema; Tokuhiro Doi; Takashi Sakai

doi:10.1246/cl.2008.90

Hydrolase-catalyzed kinetic resolution of 5-[4-(1-hydroxyethyl)phenyl]-10, 15,20-tris(pentafluorophenyl)porphyrin in ionic liquids

Tadashi Ema, Tokuhiro Doi, Takashi Sakai

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Bulky alcohol, 5-[4-(1-hydroxyethyl)phenyl]-10,15,20-tris- (pentafluorophenyl)porphyrin (1b), was synthesized, and enantiomerically pure alcohol 1b and ester 2b were obtained by a single kinetic resolution catalyzed by Candida antarctica lipase in i-Pr₂O and in [bdmim] [PF ₆].

Original language	English
Pages (from-to)	90-91
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	1
DOIs	https://doi.org/10.1246/cl.2008.90
Publication status	Published - Jan 5 2008

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Bulky alcohol, 5-[4-(1-hydroxyethyl)phenyl]-10,15,20-tris- (pentafluorophenyl)porphyrin (1b), was synthesized, and enantiomerically pure alcohol 1b and ester 2b were obtained by a single kinetic resolution catalyzed by Candida antarctica lipase in i-Pr2O and in [bdmim] [PF 6].",

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year = "2008",

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AU - Ema, Tadashi

AU - Doi, Tokuhiro

AU - Sakai, Takashi

PY - 2008/1/5

Y1 - 2008/1/5

N2 - Bulky alcohol, 5-[4-(1-hydroxyethyl)phenyl]-10,15,20-tris- (pentafluorophenyl)porphyrin (1b), was synthesized, and enantiomerically pure alcohol 1b and ester 2b were obtained by a single kinetic resolution catalyzed by Candida antarctica lipase in i-Pr2O and in [bdmim] [PF 6].

AB - Bulky alcohol, 5-[4-(1-hydroxyethyl)phenyl]-10,15,20-tris- (pentafluorophenyl)porphyrin (1b), was synthesized, and enantiomerically pure alcohol 1b and ester 2b were obtained by a single kinetic resolution catalyzed by Candida antarctica lipase in i-Pr2O and in [bdmim] [PF 6].

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Hydrolase-catalyzed kinetic resolution of 5-[4-(1-hydroxyethyl)phenyl]-10, 15,20-tris(pentafluorophenyl)porphyrin in ionic liquids

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