Hydrogen recovery by gasification and reforming technology using an effective catalyst

Katsuya Kawamoto, Hidetoshi Kuramochi, Wei Wu

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The objective of this study is to establish a potential technique for producing hydrogen-rich synthesis gas from waste wood at a lower temperature than conventional methods, as it has been proposed that the gas product be used as a fuel for a molten carbonate fuel cell (MCFC). To achieve this, experiments were conducted in a bench-scale experimental system, applying four kinds of commercial nickel (Ni)-based steam reforming catalysts. The experimental results indicated that hydrogen can be efficiently generated from biomass via high-temperature (950 °C) steam gasification. Conversely, the application of a catalyst was shown to have excellent effects on the hydrogen yield at lower temperatures. Of several catalysts used, the use of that containing a CaO component at 750 °C successfully generated hydrogen gas of about 55 vol%. The catalyst also helped reduce hydrogen sulfide that had prevented MCFC operation and toxic dioxins in the generated gas, and the performance was quantitatively evaluated.

Original languageEnglish
Title of host publication16th World Hydrogen Energy Conference 2006, WHEC 2006
Pages634-641
Number of pages8
Volume1
Publication statusPublished - 2006
Externally publishedYes
Event16th World Hydrogen Energy Conference 2006, WHEC 2006 - Lyon, France
Duration: Jun 13 2006Jun 16 2006

Other

Other16th World Hydrogen Energy Conference 2006, WHEC 2006
CountryFrance
CityLyon
Period6/13/066/16/06

Fingerprint

Reforming reactions
Gasification
Molten carbonate fuel cells (MCFC)
Recovery
Hydrogen
Catalysts
Gases
Wood wastes
Synthesis gas
Steam reforming
Hydrogen sulfide
Temperature
Biomass
Steam
Nickel
Experiments

Keywords

  • Biomass
  • Dioxins
  • Gasification and reforming
  • Hydrogen production
  • Ni-based catalyst

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Fuel Technology

Cite this

Kawamoto, K., Kuramochi, H., & Wu, W. (2006). Hydrogen recovery by gasification and reforming technology using an effective catalyst. In 16th World Hydrogen Energy Conference 2006, WHEC 2006 (Vol. 1, pp. 634-641)

Hydrogen recovery by gasification and reforming technology using an effective catalyst. / Kawamoto, Katsuya; Kuramochi, Hidetoshi; Wu, Wei.

16th World Hydrogen Energy Conference 2006, WHEC 2006. Vol. 1 2006. p. 634-641.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kawamoto, K, Kuramochi, H & Wu, W 2006, Hydrogen recovery by gasification and reforming technology using an effective catalyst. in 16th World Hydrogen Energy Conference 2006, WHEC 2006. vol. 1, pp. 634-641, 16th World Hydrogen Energy Conference 2006, WHEC 2006, Lyon, France, 6/13/06.
Kawamoto K, Kuramochi H, Wu W. Hydrogen recovery by gasification and reforming technology using an effective catalyst. In 16th World Hydrogen Energy Conference 2006, WHEC 2006. Vol. 1. 2006. p. 634-641
Kawamoto, Katsuya ; Kuramochi, Hidetoshi ; Wu, Wei. / Hydrogen recovery by gasification and reforming technology using an effective catalyst. 16th World Hydrogen Energy Conference 2006, WHEC 2006. Vol. 1 2006. pp. 634-641
@inproceedings{4e2a3001dac74d65a6398d5b65b5550b,
title = "Hydrogen recovery by gasification and reforming technology using an effective catalyst",
abstract = "The objective of this study is to establish a potential technique for producing hydrogen-rich synthesis gas from waste wood at a lower temperature than conventional methods, as it has been proposed that the gas product be used as a fuel for a molten carbonate fuel cell (MCFC). To achieve this, experiments were conducted in a bench-scale experimental system, applying four kinds of commercial nickel (Ni)-based steam reforming catalysts. The experimental results indicated that hydrogen can be efficiently generated from biomass via high-temperature (950 °C) steam gasification. Conversely, the application of a catalyst was shown to have excellent effects on the hydrogen yield at lower temperatures. Of several catalysts used, the use of that containing a CaO component at 750 °C successfully generated hydrogen gas of about 55 vol{\%}. The catalyst also helped reduce hydrogen sulfide that had prevented MCFC operation and toxic dioxins in the generated gas, and the performance was quantitatively evaluated.",
keywords = "Biomass, Dioxins, Gasification and reforming, Hydrogen production, Ni-based catalyst",
author = "Katsuya Kawamoto and Hidetoshi Kuramochi and Wei Wu",
year = "2006",
language = "English",
isbn = "9781622765409",
volume = "1",
pages = "634--641",
booktitle = "16th World Hydrogen Energy Conference 2006, WHEC 2006",

}

TY - GEN

T1 - Hydrogen recovery by gasification and reforming technology using an effective catalyst

AU - Kawamoto, Katsuya

AU - Kuramochi, Hidetoshi

AU - Wu, Wei

PY - 2006

Y1 - 2006

N2 - The objective of this study is to establish a potential technique for producing hydrogen-rich synthesis gas from waste wood at a lower temperature than conventional methods, as it has been proposed that the gas product be used as a fuel for a molten carbonate fuel cell (MCFC). To achieve this, experiments were conducted in a bench-scale experimental system, applying four kinds of commercial nickel (Ni)-based steam reforming catalysts. The experimental results indicated that hydrogen can be efficiently generated from biomass via high-temperature (950 °C) steam gasification. Conversely, the application of a catalyst was shown to have excellent effects on the hydrogen yield at lower temperatures. Of several catalysts used, the use of that containing a CaO component at 750 °C successfully generated hydrogen gas of about 55 vol%. The catalyst also helped reduce hydrogen sulfide that had prevented MCFC operation and toxic dioxins in the generated gas, and the performance was quantitatively evaluated.

AB - The objective of this study is to establish a potential technique for producing hydrogen-rich synthesis gas from waste wood at a lower temperature than conventional methods, as it has been proposed that the gas product be used as a fuel for a molten carbonate fuel cell (MCFC). To achieve this, experiments were conducted in a bench-scale experimental system, applying four kinds of commercial nickel (Ni)-based steam reforming catalysts. The experimental results indicated that hydrogen can be efficiently generated from biomass via high-temperature (950 °C) steam gasification. Conversely, the application of a catalyst was shown to have excellent effects on the hydrogen yield at lower temperatures. Of several catalysts used, the use of that containing a CaO component at 750 °C successfully generated hydrogen gas of about 55 vol%. The catalyst also helped reduce hydrogen sulfide that had prevented MCFC operation and toxic dioxins in the generated gas, and the performance was quantitatively evaluated.

KW - Biomass

KW - Dioxins

KW - Gasification and reforming

KW - Hydrogen production

KW - Ni-based catalyst

UR - http://www.scopus.com/inward/record.url?scp=84875587258&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84875587258&partnerID=8YFLogxK

M3 - Conference contribution

SN - 9781622765409

VL - 1

SP - 634

EP - 641

BT - 16th World Hydrogen Energy Conference 2006, WHEC 2006

ER -