Hydrogen azide-amine systems as an azide nucleophile for substitutions of sulfonates, halides, and vicinal disulfonates

Seiki Saito, Hajime Yokoyama, Teruhiko Ishikawa, Nobuko Niwa, Toshio Moriwake

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Hydrogen azide-alkylamine combination turned out to ensure the displacement of simple primary or secondary sulfonates, halides, and vicinal disulfonates with an azido-group in which an enhanced reactivity is generally achieved as compared with a case of traditional alkali metal azides.

Original languageEnglish
Pages (from-to)663-666
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number5
DOIs
Publication statusPublished - Jan 28 1991

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Nucleophiles
Azides
Amines
Hydrogen
Substitution reactions
Alkali Metals

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Hydrogen azide-amine systems as an azide nucleophile for substitutions of sulfonates, halides, and vicinal disulfonates. / Saito, Seiki; Yokoyama, Hajime; Ishikawa, Teruhiko; Niwa, Nobuko; Moriwake, Toshio.

In: Tetrahedron Letters, Vol. 32, No. 5, 28.01.1991, p. 663-666.

Research output: Contribution to journalArticle

Saito, Seiki ; Yokoyama, Hajime ; Ishikawa, Teruhiko ; Niwa, Nobuko ; Moriwake, Toshio. / Hydrogen azide-amine systems as an azide nucleophile for substitutions of sulfonates, halides, and vicinal disulfonates. In: Tetrahedron Letters. 1991 ; Vol. 32, No. 5. pp. 663-666.
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