Hydrido-Rhodium(I) and -Iridium(I) complex promoted ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes. Structures of intermediates and reaction pathways

Yasushi Nishihara, Chikako Yoda, Kohtaro Osakada

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

2-Phenyl-1-methylenecyclopropane and 2,2-diphenyl-1-methylenecyclopropane react with MH(CO)(PPh3)3 (M = Rh, Ir) to produce 1,3-dienes or the intermediate Rh and Ir complexes having a 3-butenyl ligand, depending on the conditions. The structures and chemical properties of the obtained complexes suggest plausible pathways for the ring-opening isomerization of the methylenecyclopropanes to the corresponding dienes.

Original languageEnglish
Pages (from-to)2124-2126
Number of pages3
JournalOrganometallics
Volume20
Issue number11
DOIs
Publication statusPublished - May 28 2001
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Hydrido-Rhodium(I) and -Iridium(I) complex promoted ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes. Structures of intermediates and reaction pathways'. Together they form a unique fingerprint.

  • Cite this