HPLC retention behaviors of π-electron rich compounds on Ni                          2+                         - and Cu                         2+                         -phthalocyanine derivatives bound to silica gels in polar eluents

Ikuko Tsukamoto; Madoka Saito; Minako Yamane; Kenji Kawata; Yuji Kitamura; Youji Kitamura; Masaki Mifune; Yutaka Saito; Jun Haginaka

doi:10.2116/analsci.22.1035

HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents

Ikuko Tsukamoto, Madoka Saito, Minako Yamane, Kenji Kawata, Yuji Kitamura, Youji Kitamura, Masaki Mifune, Yutaka Saito, Jun Haginaka

Research output: Contribution to journal › Article › peer-review

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Abstract

The effect of the central metal of columns packed with silica gels binding Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives (Ni-and Cu-PCS _D s) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCS _D s in 80% methanol showed a good linear correlation. The Cu-PCS _D column exhibited the π-π interactions for PAHs, while the Ni-PCS _D column exhibited the π-d interactions for PAHs in addition to the π-π interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCS _D columns could recognize the differences of substituents only in a polar eluent. 2006

Original language	English
Pages (from-to)	1035-1038
Number of pages	4
Journal	Analytical Sciences
Volume	22
Issue number	7
DOIs	https://doi.org/10.2116/analsci.22.1035
Publication status	Published - 2006

ASJC Scopus subject areas

Analytical Chemistry

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Tsukamoto, I., Saito, M., Yamane, M., Kawata, K., Kitamura, Y., Kitamura, Y., Mifune, M., Saito, Y., & Haginaka, J. (2006). HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents Analytical Sciences, 22(7), 1035-1038. https://doi.org/10.2116/analsci.22.1035

HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents . / Tsukamoto, Ikuko; Saito, Madoka; Yamane, Minako; Kawata, Kenji; Kitamura, Yuji; Kitamura, Youji; Mifune, Masaki; Saito, Yutaka; Haginaka, Jun.

In: Analytical Sciences, Vol. 22, No. 7, 2006, p. 1035-1038.

Research output: Contribution to journal › Article › peer-review

Tsukamoto, I, Saito, M, Yamane, M, Kawata, K, Kitamura, Y, Kitamura, Y, Mifune, M, Saito, Y & Haginaka, J 2006, ' HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents ', Analytical Sciences, vol. 22, no. 7, pp. 1035-1038. https://doi.org/10.2116/analsci.22.1035

Tsukamoto I, Saito M, Yamane M, Kawata K, Kitamura Y, Kitamura Y et al. HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents Analytical Sciences. 2006;22(7):1035-1038. https://doi.org/10.2116/analsci.22.1035

Tsukamoto, Ikuko ; Saito, Madoka ; Yamane, Minako ; Kawata, Kenji ; Kitamura, Yuji ; Kitamura, Youji ; Mifune, Masaki ; Saito, Yutaka ; Haginaka, Jun. / HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents In: Analytical Sciences. 2006 ; Vol. 22, No. 7. pp. 1035-1038.

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title = " HPLC retention behaviors of π-electron rich compounds on Ni 2+ - and Cu 2+ -phthalocyanine derivatives bound to silica gels in polar eluents ",

abstract = " The effect of the central metal of columns packed with silica gels binding Ni 2+ - and Cu 2+ -phthalocyanine derivatives (Ni-and Cu-PCS D s) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCS D s in 80% methanol showed a good linear correlation. The Cu-PCS D column exhibited the π-π interactions for PAHs, while the Ni-PCS D column exhibited the π-d interactions for PAHs in addition to the π-π interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCS D columns could recognize the differences of substituents only in a polar eluent. 2006",

author = "Ikuko Tsukamoto and Madoka Saito and Minako Yamane and Kenji Kawata and Yuji Kitamura and Youji Kitamura and Masaki Mifune and Yutaka Saito and Jun Haginaka",

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AU - Tsukamoto, Ikuko

AU - Saito, Madoka

AU - Yamane, Minako

AU - Kawata, Kenji

AU - Kitamura, Yuji

AU - Kitamura, Youji

AU - Mifune, Masaki

AU - Saito, Yutaka

AU - Haginaka, Jun

PY - 2006

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AB - The effect of the central metal of columns packed with silica gels binding Ni 2+ - and Cu 2+ -phthalocyanine derivatives (Ni-and Cu-PCS D s) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCS D s in 80% methanol showed a good linear correlation. The Cu-PCS D column exhibited the π-π interactions for PAHs, while the Ni-PCS D column exhibited the π-d interactions for PAHs in addition to the π-π interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCS D columns could recognize the differences of substituents only in a polar eluent. 2006

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HPLC retention behaviors of π-electron rich compounds on Ni 2+ - and Cu 2+ -phthalocyanine derivatives bound to silica gels in polar eluents

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HPLC retention behaviors of π-electron rich compounds on Ni ²⁺ - and Cu ²⁺ -phthalocyanine derivatives bound to silica gels in polar eluents