HPLC retention behaviors of π-electron rich compounds on Ni 2+- and Cu2+-phthalocyanine derivatives bound to silica gels in polar eluents

Ikuko Tsukamoto, Madoka Saito, Minako Yamane, Kenji Kawata, Yuji Kitamura, Youji Kitamura, Masaki Mifune, Yutaka Saito, Jun Haginaka

Research output: Contribution to journalArticle

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Abstract

The effect of the central metal of columns packed with silica gels binding Ni2+- and Cu2+-phthalocyanine derivatives (Ni-and Cu-PCSDs) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCSDs in 80% methanol showed a good linear correlation. The Cu-PCSD column exhibited the π-π interactions for PAHs, while the Ni-PCSD column exhibited the π-d interactions for PAHs in addition to the π-π interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCSD columns could recognize the differences of substituents only in a polar eluent. 2006

Original languageEnglish
Pages (from-to)1035-1038
Number of pages4
JournalAnalytical Sciences
Volume22
Issue number7
DOIs
Publication statusPublished - 2006

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Aromatic Hydrocarbons
Silica Gel
Derivatives
Electrons
Methanol
Metals
phthalocyanine

ASJC Scopus subject areas

  • Analytical Chemistry

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HPLC retention behaviors of π-electron rich compounds on Ni 2+- and Cu2+-phthalocyanine derivatives bound to silica gels in polar eluents. / Tsukamoto, Ikuko; Saito, Madoka; Yamane, Minako; Kawata, Kenji; Kitamura, Yuji; Kitamura, Youji; Mifune, Masaki; Saito, Yutaka; Haginaka, Jun.

In: Analytical Sciences, Vol. 22, No. 7, 2006, p. 1035-1038.

Research output: Contribution to journalArticle

Tsukamoto, I, Saito, M, Yamane, M, Kawata, K, Kitamura, Y, Kitamura, Y, Mifune, M, Saito, Y & Haginaka, J 2006, 'HPLC retention behaviors of π-electron rich compounds on Ni 2+- and Cu2+-phthalocyanine derivatives bound to silica gels in polar eluents', Analytical Sciences, vol. 22, no. 7, pp. 1035-1038. https://doi.org/10.2116/analsci.22.1035
Tsukamoto, Ikuko ; Saito, Madoka ; Yamane, Minako ; Kawata, Kenji ; Kitamura, Yuji ; Kitamura, Youji ; Mifune, Masaki ; Saito, Yutaka ; Haginaka, Jun. / HPLC retention behaviors of π-electron rich compounds on Ni 2+- and Cu2+-phthalocyanine derivatives bound to silica gels in polar eluents. In: Analytical Sciences. 2006 ; Vol. 22, No. 7. pp. 1035-1038.
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AU - Tsukamoto, Ikuko

AU - Saito, Madoka

AU - Yamane, Minako

AU - Kawata, Kenji

AU - Kitamura, Yuji

AU - Kitamura, Youji

AU - Mifune, Masaki

AU - Saito, Yutaka

AU - Haginaka, Jun

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