Highly sensitive chiral shift reagent bearing two zinc porphyrins

Tadashi Ema, Nozomi Ouchi, Tokuhiro Doi, Toshinobu Korenaga, Takashi Sakai

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

(Chemical Equation Presented) A new type of chiral receptor (R,R)- or (S,S)-1b with C2 symmetry was synthesized. An induced-fit type of binding behavior of 1b for diamines was revealed by CD spectroscopy. NMR studies demonstrated that 1b can function as a highly sensitive chiral shift reagent for the determination of the enantiomeric purity of chiral diamines, aziridine, and isoxazoline at the microgram level.

Original languageEnglish
Pages (from-to)3985-3988
Number of pages4
JournalOrganic Letters
Volume7
Issue number18
DOIs
Publication statusPublished - Sep 1 2005

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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