Highly ordered TiO2 nanotube arrays with controllable length for photoelectrocatalytic degradation of phenol

Zhaoyue Liu, Xintong Zhang, Shunsuke Nishimoto, Ming Jin, Donald A. Tryk, Taketoshi Murakami, Akira Fujishima

Research output: Contribution to journalArticle

337 Citations (Scopus)

Abstract

Highly ordered TiO2 nanotube array prepared by a potentiostatic anodization shows a considerable potential for improving the transport of the photogenerated electrons in the TiO2 film, since the ordered architecture can provide a unidirectional electric channel and reduce the grain boundaries. Here, we report on the application of highly ordered TiO2 nanotube arrays with different lengths for the photoelectrocatalytic degradation of phenol. The lengths of the nanotube arrays can be controlled by the electrolyte media, anodization time, or both. The photoelectrocatalytic activity shows a dependence on the length of the nanotube arrays. Under 3.1 mW/cm2 irradiance of ultraviolet light, a short nanotube array shows better photoelectrocatalytic activity than a long nanotube array, which can be explained by the reduced recombination effects. When compared with a P25 TiO2 particulate film with similar thickness and geometric area, the nanotube array shows a stronger attachment to the parent titanium substrate and a better photoelectrocatalytic activity for phenol degradation owing to the improved electron transport and reduced charge recombination. This superior electron transport is further supported by the remarkably enhanced anodic photocurrent response in the degradation of phenol.

Original languageEnglish
Pages (from-to)253-259
Number of pages7
JournalJournal of Physical Chemistry C
Volume112
Issue number1
DOIs
Publication statusPublished - Jan 10 2008
Externally publishedYes

Fingerprint

Phenol
phenols
Nanotubes
Phenols
nanotubes
degradation
Degradation
electrons
Titanium
Photocurrents
irradiance
ultraviolet radiation
particulates
Electrolytes
attachment
photocurrents
Grain boundaries
grain boundaries
titanium
electrolytes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Highly ordered TiO2 nanotube arrays with controllable length for photoelectrocatalytic degradation of phenol. / Liu, Zhaoyue; Zhang, Xintong; Nishimoto, Shunsuke; Jin, Ming; Tryk, Donald A.; Murakami, Taketoshi; Fujishima, Akira.

In: Journal of Physical Chemistry C, Vol. 112, No. 1, 10.01.2008, p. 253-259.

Research output: Contribution to journalArticle

Liu, Zhaoyue ; Zhang, Xintong ; Nishimoto, Shunsuke ; Jin, Ming ; Tryk, Donald A. ; Murakami, Taketoshi ; Fujishima, Akira. / Highly ordered TiO2 nanotube arrays with controllable length for photoelectrocatalytic degradation of phenol. In: Journal of Physical Chemistry C. 2008 ; Vol. 112, No. 1. pp. 253-259.
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