TY - JOUR
T1 - High-Spin Iron(III) Complex with 2-(2-Imidazolyl)phenolate
AU - Mitsuhashi, Ryoji
AU - Hosoya, Satoshi
AU - Suzuki, Takayoshi
AU - Mikuriya, Masahiro
N1 - Funding Information:
The present work was partially supported by Grants-in-Aid for Scientific Research No. 19K15525 from the MEXT, Japan.
Publisher Copyright:
© The Japan Society for Analytical Chemistry
PY - 2022
Y1 - 2022
N2 - The crystal structure of tris{2-(2-imidazolyl)phenolato}iron(III), which was synthesized by a reaction of Fe(BF4)2•6H2O and 2-(2-imidazolyl)phenolate in methanol, was determined by X-ray crystallography. The compound crystallized in the trigonal space group R-3 and Z = 6 with cell parameters a = 15.830(3)Å, c = 19.973(4)Å, V = 4334.4(18)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0385 and 0.1005, respectively, for all 2337 independent reflections. The iron atom is coordinated by three 2-(2-imdazolyl)phenolato ligands in a facial N3O3 configuration, where the solvent methanol molecules are hydrogen-bonded to the phenolato-oxygen atoms.
AB - The crystal structure of tris{2-(2-imidazolyl)phenolato}iron(III), which was synthesized by a reaction of Fe(BF4)2•6H2O and 2-(2-imidazolyl)phenolate in methanol, was determined by X-ray crystallography. The compound crystallized in the trigonal space group R-3 and Z = 6 with cell parameters a = 15.830(3)Å, c = 19.973(4)Å, V = 4334.4(18)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0385 and 0.1005, respectively, for all 2337 independent reflections. The iron atom is coordinated by three 2-(2-imdazolyl)phenolato ligands in a facial N3O3 configuration, where the solvent methanol molecules are hydrogen-bonded to the phenolato-oxygen atoms.
UR - http://www.scopus.com/inward/record.url?scp=85129362446&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85129362446&partnerID=8YFLogxK
U2 - 10.2116/XRAYSTRUCT.38.37
DO - 10.2116/XRAYSTRUCT.38.37
M3 - Article
AN - SCOPUS:85129362446
SN - 1883-3578
VL - 38
SP - 37
EP - 39
JO - X-ray Structure Analysis Online
JF - X-ray Structure Analysis Online
ER -