TY - JOUR
T1 - High-resolution spectroscopy of buffer-gas-cooled phthalocyanine
AU - Miyamoto, Yuki
AU - Tobaru, Reo
AU - Takahashi, Yuiki
AU - Hiramoto, Ayami
AU - Iwakuni, Kana
AU - Kuma, Susumu
AU - Enomoto, Katsunari
AU - Baba, Masaaki
N1 - Funding Information:
We would like to thank Prof. Doyle, Prof. Takahashi, Prof. Hutzler, Prof. Uetake, and Prof. Takasu for their kind cooperation. Y.M. would like to thank the members of Core for Quantum Universe (RIIS, Okayama University). Y.T. would like to thank the Masason Foundation for their financial support. This work was supported by JSPS KAKENHI Grant Nos. 18H01229 and 22H01249, and Masason Foundation. We would like to thank Editage ( www.editage.com ) for English language editing.
Funding Information:
We would like to thank Prof. Doyle, Prof. Takahashi, Prof. Hutzler, Prof. Uetake, and Prof. Takasu for their kind cooperation. Y.M. would like to thank the members of Core for Quantum Universe (RIIS, Okayama University). Y.T. would like to thank the Masason Foundation for their financial support. This work was supported by JSPS KAKENHI Grant Nos. 18H01229 and 22H01249, and Masason Foundation. We would like to thank Editage (www.editage.com) for English language editing.
Publisher Copyright:
© 2022, The Author(s).
PY - 2022/12
Y1 - 2022/12
N2 - For over five decades, studies in the field of chemical physics and physical chemistry have primarily aimed to understand the quantum properties of molecules. However, high-resolution rovibronic spectroscopy has been limited to relatively small and simple systems because translationally and rotationally cold samples have not been prepared in sufficiently large quantities for large and complex systems. In this study, we present high-resolution rovibronic spectroscopy results for large gas-phase molecules, namely, free-base phthalocya-nine (FBPc). The findings suggest that buffer-gas cooling may be effective for large molecules introduced via laser ablation. High-resolution electronic spectroscopy, combined with other experimental and theoretical studies, will be useful in understanding the quantum properties of molecules. These findings also serve as a guide for quantum chemical calculations of large molecules.
AB - For over five decades, studies in the field of chemical physics and physical chemistry have primarily aimed to understand the quantum properties of molecules. However, high-resolution rovibronic spectroscopy has been limited to relatively small and simple systems because translationally and rotationally cold samples have not been prepared in sufficiently large quantities for large and complex systems. In this study, we present high-resolution rovibronic spectroscopy results for large gas-phase molecules, namely, free-base phthalocya-nine (FBPc). The findings suggest that buffer-gas cooling may be effective for large molecules introduced via laser ablation. High-resolution electronic spectroscopy, combined with other experimental and theoretical studies, will be useful in understanding the quantum properties of molecules. These findings also serve as a guide for quantum chemical calculations of large molecules.
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U2 - 10.1038/s42004-022-00783-4
DO - 10.1038/s42004-022-00783-4
M3 - Article
AN - SCOPUS:85142932989
SN - 2399-3669
VL - 5
JO - Communications Chemistry
JF - Communications Chemistry
IS - 1
M1 - 161
ER -