High-resolution infrared spectra of carbonyl sulfide solvated with helium atoms

Jian Tang, A. R W McKellar

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

High-resolution infrared spectra of carbonyl sulfide solvated with helium atoms was studied. The vibrational frequencies were observed to move higher frequencies, continuing the shift previously observed for the binary complex, He-OCS. The results indicate that the first five helium atoms clustered around OCS induce a progressive positive shift of the O-C vibrational frequency.

Original languageEnglish
Pages (from-to)5467-5477
Number of pages11
JournalThe Journal of Chemical Physics
Volume119
Issue number11
DOIs
Publication statusPublished - Sep 15 2003
Externally publishedYes

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Helium
Vibrational spectra
helium atoms
sulfides
infrared spectra
Infrared radiation
Atoms
shift
high resolution
carbonyl sulfide

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

High-resolution infrared spectra of carbonyl sulfide solvated with helium atoms. / Tang, Jian; McKellar, A. R W.

In: The Journal of Chemical Physics, Vol. 119, No. 11, 15.09.2003, p. 5467-5477.

Research output: Contribution to journalArticle

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